二元酸单酯合成研究进展  

Progress on Synthesizing Dicarboxylic Acid Monoester

作　　者：陈永钢[1] 尹志刚[1] 钱恒玉[1] 张同艳[1] 余述燕[1] 

机构地区：[1]郑州轻工业学院材料与化学工程学院,河南郑州450002

出　　处：《安阳师范学院学报》2015年第2期14-22,共9页Journal of Anyang Normal University

摘　　要：按照二元酸单酯的不同类别,综述了它们不同的合成方法。主要包括控制醇酸比直接酯化法;二元酸双酯部分水解法;二元酸(酐)和二元酸双酯酯交换法;一元酸酯催化氧化等方法。评价了每种合成方法的优缺点,对二元酸单酯的工业化合成提供了理论指导。Various synthetic techniques of dicarboxylic monoester are reviewed according to their chemical structure differences in this paper,such as direct esterification between dicarboxylic acid and alcohol in the condition of controlling the ratio of alcohol to acid,partial hydrolysis of dicarboxylic diester,interesterification between dicarboxylic diester and its acid or anhydride and the catalytic oxidation of some carboxylic ester with special chemical structure and so on. Their typical characteristics are also evaluated simply,which provide some theoretical guidances of synthesizing dicarboxylic monoester on an industrial scale.

关 键 词：二元酸单酯 合成 进展 

分 类 号：TQ225.14[化学工程—有机化工]