流动对316L/2205和431/2205不锈钢在3.5% NaCl溶液中电偶腐蚀的影响  

Effect of Flowing Rate on Galvanic Corrosion Associated with 316L/2205 and 431/2205 Stainless Steel Couples in 3.5% NaCl Solution

作　　者：王健[1] 程从前[1] 王冬颖[2] 姚景文 关锰[2] 赵杰[1] 

机构地区：[1]大连理工大学材料科学与工程学院,大连116085 [2]沈阳鼓风机集团有限公司核电事业部,沈阳110001

出　　处：《腐蚀与防护》2015年第5期442-447,共6页Corrosion & Protection

基　　金：国家自然科学基金(51101024)

摘　　要：采用动电位极化、电偶电流、腐蚀形貌分析等方法研究了在3.5%NaCl溶液中介质流动对316L/2205和431/2205不锈钢电偶腐蚀的影响。与42CrMo/316L偶对对比发现316L/2205、431/2205和42CrMo/316L电偶中316L、431和42CrMo均作为阳极,其腐蚀受到加速,三种偶对的电偶腐蚀倾向大小为:316L/2205<431/2205<42CrMo/316L;电偶电流测量发现介质流动可以增大三种偶对的电偶电流,偶对431/2205存在电偶电流和电位暂态峰。腐蚀形貌分析发现,静止条件下316L、2205和431不锈钢没有明显的腐蚀,42CrMo钢表面覆盖锈蚀层;流动条件下431不锈钢表面点蚀坑形成并附着腐蚀产物,42CrMo表面局部形成锈蚀层,结合形貌分析认为,431/2205偶对中电流暂态峰的出现与蚀坑中锈蚀层的形成有关。Effect of flowing on galvanic corrosion of 316L/2205 and 431/2205 couples in 3.5% NaCl solution was investigated by potentiodynamic polarization, galvanic current and corrosion morphology analyses. The galvanic behavior of these couples was compared with that of 42CrMo/316L couple. The results showed that 316L, 431 and 42CrMo were anode, respectively. The galvanic corrosion tendency of these couples was shown as follows： 316L/ 2205〈 431/2205〈 42CrMo/316L. The galvanic current measurement revealed that flowing increased the galvanic current. Oscillation peaks in both galvanic potential and current curves were observed under flowing condition for the 431/2205 couple. Corrosion morphology analyses indicated that there were no obvious corrosion on 316L, 431 and 2205 stainless steels in the static solution and a rust layer formed on the surface of 42CrMo steel. Under flowing condition, pits covered with rust on 431 stainless steel were observed, surface of 42CrMo steel was covered with corrosion products. It is considered that the oscillation peaks of current density for 431/2205 couples is possibly attributed to the formation of rust on the pits Under flowing condition.

关 键 词：不锈钢 电偶腐蚀 流动 

分 类 号：TG172[金属学及工艺—金属表面处理]