A Novel 2D→3D Network with the Coexistence of Polythreading and Inclined Polycatenation Constructed by the Tripodal Linker  

作　　者：周杰 江波 刘赛 马春 胡劲松 

机构地区：[1]School of Chemical Engineering, Anhui University of Science and Technology [2]State Key Laboratory of Coordination Chemistry, Nanjing University

出　　处：《Chinese Journal of Structural Chemistry》2015年第4期536-542,共7页结构化学（英文）

基　　金：Supported by the National Natural Science Foundation of China(21301005);the Natural Science Foundation of Anhui Province(1408085QB31)

摘　　要：A new cadmium（Ⅱ） coordination polymer with unique structure was synthesized under diffusion process by employing triangular N-containing ligand tris（4-（pyridyl） phenyi） amine （Tppa）. Complex 1 crystallizes in the space group Pbcn, with a = 28.906（3）, b = 13.5294（14）, c = 17.8727（18） A, V= 6989.7（12） A^3, C66H48CdCl2N8, Mr = 1136.42, De = 1.080 g/cm^3, F（000） = 2328, μ= 0.428 mm^-1 and Z = 4. Complex 1 features a 2D → 3D framework with the coexistence of inclined polycatenation and polythreading. In addition, the luminescent property of complex 1 was studied.A new cadmium（Ⅱ） coordination polymer with unique structure was synthesized under diffusion process by employing triangular N-containing ligand tris（4-（pyridyl） phenyi） amine （Tppa）. Complex 1 crystallizes in the space group Pbcn, with a = 28.906（3）, b = 13.5294（14）, c = 17.8727（18） A, V= 6989.7（12） A^3, C66H48CdCl2N8, Mr = 1136.42, De = 1.080 g/cm^3, F（000） = 2328, μ= 0.428 mm^-1 and Z = 4. Complex 1 features a 2D → 3D framework with the coexistence of inclined polycatenation and polythreading. In addition, the luminescent property of complex 1 was studied.

关 键 词：coordination polymer polycatenation polythreading PHOTOLUMINESCENT 

分 类 号：O634[理学—高分子化学]