Preparation of aromatic nitriles via direct oxidative conversion of benzyl alcohols,aldehydes and amines with pentylpyridinium tribromide in aqueous NH_4OAc  

作　　者：Ghodsieh Bagherzade Abbas Zali Arash Shokrolahi 

机构地区：[1]Department of Chemistry,Faculty of Sciences,University of Birjand [2]Department of Chemistry,Malek-ashtar University of Technology

出　　处：《Chinese Chemical Letters》2015年第5期603-606,共4页中国化学快报（英文版）

摘　　要：Pentylpyridinium tribromide and aqueous ammonium acetate was used for the rapid oxidative conversion of benzyl alcohols, benzaldehydes and benzyl amines to the corresponding benzonitriles in good to excellent yields. This simple, mild and one-pot system provides easy workup and separation of the products.Pentylpyridinium tribromide and aqueous ammonium acetate was used for the rapid oxidative conversion of benzyl alcohols, benzaldehydes and benzyl amines to the corresponding benzonitriles in good to excellent yields. This simple, mild and one-pot system provides easy workup and separation of the products.

关 键 词：Nitriles Alcohols Amines Aldehydes Pentylpyridinium tribromide 

分 类 号：TQ203[化学工程—有机化工]