浓硫酸高温焙烧稀土精矿水浸液镁皂化废水的资源化  

Resource Recovery of Magnesium Saponification Wastewater of Leaching Solution of Sulfuric Acid Calcining RE Concentrate

作　　者：刘磊 谢军 李赫 柳凌云 侯少春 萨如拉 姚龙君 

机构地区：[1]包头华美稀土高科有限公司,内蒙古包头014010 [2]包头稀土研究院,内蒙古包头014030

出　　处：《湿法冶金》2015年第3期242-244,共3页Hydrometallurgy of China

摘　　要：研究了包头稀土精矿浓硫酸高温焙砂水浸液经过镁皂化萃取转型产生的镁皂废水的资源化全循环工艺,针对镁皂废水的净化除杂、晶体制备、晶体煅烧等进行了可行性研究。结果表明:控制草酸用量为理论量的2倍,镁皂废水的氧化钙质量浓度<0.2g/L;净化后的镁皂废水经陶瓷膜过滤、纳滤膜浓缩得到的透析水可回用于水浸,浓水进入蒸发系统回收硫酸镁和冷凝水;冷凝水回用于水浸,硫酸镁晶体与碳粉在850℃下煅烧8h可制备氧化镁;所得氧化镁的CAA活性值为109s,MgO质量分数为96.84%,CaO质量分数为0.52%,可用于生产稀土;硫酸镁煅烧产生的二氧化硫在钒触媒催化作用下可转化成70%的硫酸,回用于焙烧。该工艺可实现镁皂废水资源化全循环利用。The resource recovery of magnesium saponification wastewater of leaching solution of sulfuric acid calcining rare earth concentrate was studied mainly involving the progresses of purification ,crystallization ,calcination and so on .T he experiment results show w hen the actual amount of oxalic acid is twice the theoretical amount ,the content of CaO in the magnesium saponification wastewater can be reduced to less than 2% .Then the dialysis water by ceramic membrane and nanofiltration membrane can be used in the process of RE leaching ,and the concentrate water can be used to recover magnesium sulfate and condensate water in evaporation system .The condensate water can used in the process of RE leaching .The magnesium sulfate crystal with carbon powder is calcinated for 8 h at 850 ℃ ,the magnesium oxide can be obtained .The analysis results show that in the magnesium oxide ,the content of MgO and CaO is 96 .84% and 0 .52% ,respectively .The value of CAA for the magnesium oxide is 109 s .Sulfur dioxide produced in the process of calcination can be conversed into 70% sulfuric acid used in the process of sulfuric acid calcinating RE concentrate .

关 键 词：稀土精矿 镁皂化 废水 资源化 循环利用 

分 类 号：X758[环境科学与工程—环境工程]