一种新型有机硅-氟化合物的合成及应用研究  

Synthesis and Application of a New Organic Silicone-fluoride Compound

作　　者：徐山山[1,2] 雷志涛 刘群[1] 宋欣荣[1] 

机构地区：[1]湖南工程学院化学化工学院,湘潭411104 [2]浙江汉邦化工有限公司,嘉兴314500

出　　处：《湖南工程学院学报（自然科学版）》2015年第2期62-64,90,共4页Journal of Hunan Institute of Engineering(Natural Science Edition)

基　　金：湖南省自然科学基金资助项目(10JJ6018)

摘　　要：以三乙胺为催化剂,六氟丙烯三聚体和羟基硅油等为原料,合成了一种新的有机硅-氟化合物并通过FTIR、核磁共振光谱等对其进行结构表征和应用效果测试.研究发现,当整理液中有机硅-氟化合物的含量为15g/L时,经其整理液整理后棉织物的拒水分数可以达到90分,拒油级别能达到4级,织物柔软性能达到5分等.A new organic silicone-fluoride compound is synthesized by hexafluoropropylene trimer and hydroxyl silicone oil under triethylamine as catalyst. The structure of synthetic product is characterized by FTIR spectra and 13CNMR, and applied effect of synthetic product on cotton fiber is tested. Results shown that when the content of the organic silicone-fluoride compound in finishing liquid is 15g/L, water-repel- lency scores can reach 90 points, oil-repellency level can reach grade 4, softness can reach 5 points of cotton fabrics.

关 键 词：六氟丙烯三聚体 有机硅-氟化合物 合成 棉织物 应用 

分 类 号：TQ264.1[化学工程—有机化工]