铁咔咯配合物在有机合成中的催化应用  

Catalytic Application of Iron Corrole Complexes in Organic Synthesis

作　　者：邹怀波[1] 汪华华[1] 梅光泉[2] 刘海洋[1] 张启光 

机构地区：[1]华南理工大学化学系,广州510640 [2]宜春学院江西省高校应用化学与化学生物学重点实验室,宜春336000 [3]Department of Chemistry, Michigan State University, E. Lansing, MI 48824, USA

出　　处：《化学进展》2015年第6期666-674,共9页Progress in Chemistry

基　　金：国家自然科学基金项目(No.21171057,21371059,21261024)资助~~

摘　　要：铁咔咯配合物的制备及其催化活性研究是当今卟啉化学的前沿课题之一。本文综述了近年来铁咔咯配合物在有机合成中的催化应用,重点归纳评述了它们在氧化反应,烯烃的环丙烷化、氮杂环丙烷化,N—H键、S—H键和C—H键的插入反应,[4+2]环加成反应及共聚反应中的催化活性,分析了目前铁咔咯配合物在催化研究方面存在的问题并展望了其发展的方向。Study on the preparation and catalytic activities of iron corrole has become one of the hot topics of porphyrin chemistry. In this paper, the recent progress about catalytic application of iron corrole in organic synthesis has been reviewed, with an emphasis on the oxidation, cyclopropanation and aziridination of olefin, insertion reactions involving N-H, S-H and C-H bonds, [4 ＋ 2 ] cycloaddition as well as copolymerization of epoxides with carbon dioxide. The problems of iron corroles in catalysis and several directions have also been addressed.

关 键 词：咔咯 铁配合物 催化 有机合成 

分 类 号：O641.3[理学—物理化学] O614.811[理学—化学]