Hydrothermal Syntheses,Crystal Structures,TGA and Electrochemistry Properties of Two Metal-organic Coordination Compounds Based on 4'-((1H-1,2,4-triazol-1-yl)methyl)-[1,1'-biphenyl]-2-carbonitril  

作　　者：黄登登 潘其建 丹媛媛 陈立庄 

机构地区：[1]School of Environmental and Chemical Engineering,Jiangsu University of Science and Technology

出　　处：《Chinese Journal of Structural Chemistry》2015年第1期123-132,共10页结构化学（英文）

基　　金：Supported by the National Natural Science Foundation of China(No.21201087);NSF of Jiangsu Province(BK20131244 and BK20130460);the Foundation of Jiangsu Educational Committee(11KJB150004);the Qing Lan Project of Jiangsu Province and Jiangsu Overseas Research&Training Program for University Prominent Young&Middle-aged Teacher and Presidents,the Innovation Program of Graduate Students in Jiangsu Province(SJZZ-0142)

摘　　要：Two novel metal-organic coordination compounds with molecular structures of {[Co（TMBC）4Cl2]·2H2O}（1） and {[Ni（TMBC）4Cl2]·2H2O}（2）（TMBC = 4＇-（（1H-1,2,4-triazol-1-yl）methyl）-[1,1＇-biphenyl]-2-carbonitrile）, have been synthesized under hydrothermal conditions of Co Cl2·6H2O and Ni Cl2·6H2O with 4＇-（（1H-1,2,4-triazol-1-yl）methyl）-[1,1＇-biphenyl]-2-carbonitrile, respectively. Both compounds crystallize in triclinic systems, space group P 1. They are characterized by single-crystal X-ray diffraction analysis, elemental analysis, IR spectroscopy and TGA. Moreover, their electrochemical behaviors have also been studied in different electrolyte solutions, respectively.Two novel metal-organic coordination compounds with molecular structures of {[Co（TMBC）4Cl2]·2H2O}（1） and {[Ni（TMBC）4Cl2]·2H2O}（2）（TMBC = 4＇-（（1H-1,2,4-triazol-1-yl）methyl）-[1,1＇-biphenyl]-2-carbonitrile）, have been synthesized under hydrothermal conditions of Co Cl2·6H2O and Ni Cl2·6H2O with 4＇-（（1H-1,2,4-triazol-1-yl）methyl）-[1,1＇-biphenyl]-2-carbonitrile, respectively. Both compounds crystallize in triclinic systems, space group P 1. They are characterized by single-crystal X-ray diffraction analysis, elemental analysis, IR spectroscopy and TGA. Moreover, their electrochemical behaviors have also been studied in different electrolyte solutions, respectively.

关 键 词：cobalt nickel hydrothermal condition crystal structure electrochemical properties 

分 类 号：O627[理学—有机化学]