Temperature Dependent Assembly, Structural Diversity and Luminescent Property in Two Novel Cd Coordination Polymers  

作　　者：WANG Jian LIN Ping DU Shao-Wu 

机构地区：[1]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences [2]Graduate University of Chinese Academy of Sciences

出　　处：《Chinese Journal of Structural Chemistry》2015年第6期945-952,共8页结构化学（英文）

基　　金：supported by the National Basic Research Program of China(973 Program,2012CB821702);the National Natural Science Foundation of China(21233009 and 21173221);the State Key Laboratory of Structural Chemistry

摘　　要：Temperature dependent assembly of two novel Cd coordination polymers with the phen and H2MIP ligands （phen = 1,10-phenanthrolion and H2MIP = 5-methyl-isophthalic acid）, formulated as Cd2（MIP）2（phen）2 （1） and Cd3（MIP）3（H2MIP）（phen）2 （2）. They have been structurally characterized by single-crystal X-ray diffraction, elemental analysis, FT-IR spectra and TGA. 1 crystallizes in the monoclinic space group P2/n, while 2 crystallizes in the triclinic space group P1. 1 shows a 2D （two-dimensional） plane and 2 shows a 1D （one-dimensional） chain. In addition, their solid-state luminescent properties have also been investigated.Temperature dependent assembly of two novel Cd coordination polymers with the phen and H2MIP ligands （phen = 1,10-phenanthrolion and H2MIP = 5-methyl-isophthalic acid）, formulated as Cd2（MIP）2（phen）2 （1） and Cd3（MIP）3（H2MIP）（phen）2 （2）. They have been structurally characterized by single-crystal X-ray diffraction, elemental analysis, FT-IR spectra and TGA. 1 crystallizes in the monoclinic space group P2/n, while 2 crystallizes in the triclinic space group P1. 1 shows a 2D （two-dimensional） plane and 2 shows a 1D （one-dimensional） chain. In addition, their solid-state luminescent properties have also been investigated.

关 键 词：temperature dependent assembly 2D 1D LUMINESCENT 

分 类 号：O634[理学—高分子化学]