4-十四烷基酚的合成及条件优化  

The Synthesis of 4- Tetradecylphenol and Condition Optimization

作　　者：丁伟[1] 武松[1] 李博洋[1] 张瀚文[1] 宋成龙[1] 

机构地区：[1]东北石油大学化学化工学院石油与天然气化工省重点实验室,黑龙江大庆163318

出　　处：《山东化工》2015年第12期1-2,6,共3页Shandong Chemical Industry

摘　　要：以十四酰氯与苯酚反应得到苯酚酯,再与无水三氯化铝进行Fries重排生成烷基酮,后经黄鸣龙还原反应得到烷基酚。通过对Fries重排反应的反应时间、催化剂用量、是否添加溶剂进行研究得到较好的合成条件,合成出了烷基酚中间体。In the reaction, tetradecanoyl chloride and phenol reacted to obtain phenol ester, then we use anhydrous aluminium chloride as catalyst to generate alkyl ketones which called Fries - rearrangement , after that we conducted Huang Minion reduction reaction to obtain 4 - tetradecylphenol. The reaction time, the amount of catalyst of fries rearrangement , whether to add solvent were studied to obtain better synthesis conditions for the synthesis of 4 - tetradecylphenol.

关 键 词：酰基化 FRIES重排 黄鸣龙还原 

分 类 号：TQ243.1[化学工程—有机化工] TQ243.2