仲胺修饰聚硅氧烷调控的一锅法Cu(I)催化多组分点击反应（英文）  

One-pot Cu(I)-catalyzed Multicomponent Click Reaction Mediated by Secondary Amine-functional Polysiloxane

作　　者：王彩云[1] 王丁[1] 邹劲峰[1] 张丽君[2] 郑战江[1] 杨科芳[1] 徐利文[1] 徐征[1] 

机构地区：[1]杭州师范大学有机硅化学及材料技术教育部重点实验室,浙江杭州311121 [2]浙江农林大学浙江省林业生物质化学利用重点实验室,浙江临安311300

出　　处：《杭州师范大学学报（自然科学版）》2015年第3期229-238,共10页Journal of Hangzhou Normal University(Natural Science Edition)

基　　金：Supported by the National Natural Science Foundation of China(21173064,51303043);Hangzhou Science and Technology Program(20130432B06)

摘　　要：在仲胺修饰聚硅氧烷的调控下,Cu(I)可在温和的条件下催化炔、叠氮化钠以及有机溴化合物的点击反应,收率较高,反应底物有比较广的适用性,不同的底物可以中等到较高的收率得到对应产物.The secondary amine‐functional polysiloxane is found to be efficient macromolecular ligand to accelerate copper（I）‐catalyzed multicomponent cycloaddition of sodium azide ,organic halide ,and alkynes ,in which the one‐pot three‐component click reaction can be performed smoothly with the mediation of secondary amine functional polysiloxane to give various 1 ,2 ,3‐triazoles in moderate to good yields .

关 键 词：仲胺修饰聚硅氧烷 高分子配体 三唑 点击反应 

分 类 号：O634.41[理学—高分子化学]