基于数值模拟的碳纳米管水泥基复合材料导电机理分析  

Conductive mechanism analysis of carbon nanotube cement-based composites based on numerical simulation

作　　者：董素芬[1,2] 张立卿[1] 李祯[3] 姜海峰[4] 韩宝国[1] 

机构地区：[1]大连理工大学土木工程学院,辽宁大连116024 [2]内蒙古科技大学建筑与土木工程学院,内蒙古包头014010 [3]哈尔滨工程大学航天与建筑工程学院,哈尔滨150001 [4]哈尔滨工业大学土木工程学院,哈尔滨150090

出　　处：《功能材料》2015年第11期11021-11026,共6页Journal of Functional Materials

基　　金：国家自然科学基金资助项目(51178148);教育部"新世纪优秀人才支持计划"资助项目(NCET-11-0798);国家科技支撑计划资助项目(2011BAK02B01)

摘　　要：通过建立碳纳米管水泥基复合材料的代表性体积单元模型,基于有限元法进行了有效介质方程导电模型的拟合和感知性能的计算,得到碳纳米管水泥基复合材料在荷载作用下的应力与体积电阻率的关系,在此基础上了分析了碳纳米管水泥基复合材料的导电机理. 研究结果表明,碳纳米管体积掺量为1.50%时,随碳纳米管直径减小及长径比增大,有限元数值解的有效介质方程拟合值变化不大,这是因为1.5%的掺量已超过渗流阈值且有限元分析只考虑接触导电;当碳纳米管的体积掺量在0.31%-1.33%范围内时,碳纳米管水泥基复合材料的感知性能满足Simmons隧道效应普适方程.To analyze the conductive mechanism of carbon nanotube cement-based composites,the represent volume element model of carbon nanotube cement-based composites was established.By fitting general effective media equation and calculating sensing property with finite element method,the relationship between volume resistivity and stress was obtained.The simulated results show that when the volume content of carbon nanotube is 1.50%,the fitted value of the finite element numerical solution changes a little with the decreasing of the carbon nanotube diameter and the increasing of the aspect ratio.The observed behavior is because the value of 1.5vol% exceeds the percolation threshold and only contact conduction is considered in the finite element analysis.When the carbon nanotube content is from 0.31% to 1.33vol%,the sensing property of carbon nanotube cement-based composites satisfies simmons tunnel effect universal equation.

关 键 词：水泥基复合材料 碳纳米管 导电机理 有限元分析 隧道效应 

分 类 号：TB332[一般工业技术—材料科学与工程]