一种具有潜在的电致发光性能的苝酰亚胺衍生物的合成及其薄膜的电化学制备  

Synthesis of perylene diimide derivative with potentially electroluminescent performance and fabrication of its film with electrochemical deposition method

作　　者：郭晓迪[1] 王佳[1] 张海全[1] 

机构地区：[1]燕山大学亚稳材料制备技术与科学国家重点实验室,河北秦皇岛066004

出　　处：《燕山大学学报》2015年第1期84-87,94,共5页Journal of Yanshan University

基　　金：国家自然科学基金资助项目(51173155)

摘　　要：以3,4,9,10-苝四酸二酐为原料,合成了苝酰亚胺衍生物—N,N’-二异辛基1,7-(对叔丁基苯氧基)-3,4,9,10-苝四羧酸二酰亚胺(PITD),利用傅立叶红外光谱(FT-IR),核磁共振氢谱(H1NMR)表征了中间产物及目标产物的化学结构。通过PITD在二氯甲烷稀溶液和滴膜的紫外吸收光谱和荧光光谱的分析,证明PITD是一种具有电致发光性能的化合物,然后通过水合肼的作用将PITD制成用于电沉积制膜的电解液,利用XRD和SEM研究了电沉积法制备PITD薄膜的结构及形貌。Perylene Diimide Derivative with potentially electroluminescent performance,N,N'-bis-iso-octyl-1,7-di( 4-t-butylphenoxy)-perylene-3,4,9,10-tertracarboxylic acid diimide,are synthesized from 3,4,9,10-perylenetraboxylic dianhydride. The structures are characterized by FT-IR and H1 NMR. It is proved that PITD has electroluminescent property by characteriation of UV-Vis and fluorescence spectrum of solution and film of PITD. Then Perylene Diimide Derivative is made for electrodeposition films after adding hydrazine hydrate. The optical properties of them are investigated by UV-Vis. On the basis of the solvent,the films are made on ITO films by electrodeposition and characterized by UV-Vis,XRD and SEM.

关 键 词：N N’-二异辛基-1 7-(对叔丁基苯氧基)-3 4 9 10-苝四羧酸二酰亚胺 电沉积 薄膜 

分 类 号：O649.5[理学—物理化学]