羰基化合成甲酸钙实验安全分析及对策  

Safety Analysis and Countermeasures of Carbonylation Synthesis of Calcium Formate from Carbon Monoxide and Calcium Hydroxide

作　　者：马航[1,2] 冯霄[3] 杨亚斌[2] 曾波[2] 

机构地区：[1]西安交通大学化学工程与技术学院,西安710049 [2]云南省化工研究院,昆明650228 [3]中国石油大学(北京)新能源研究院,北京102249

出　　处：《云南化工》2015年第3期34-38,共5页Yunnan Chemical Technology

摘　　要：使用一氧化碳和氢氧化钙羰基化合成甲酸钙工艺是国内较为关注的研究热点。由于羰基化合成甲酸钙需要在高温、高压条件下进行,而反应原料一氧化碳又是易燃、易爆、有毒的危险化学品,因此,开展合成试验具有较大的危险性,必须要认真进行系统安全分析并制定相应安全对策及规程。对使用釜式反应试验装置合成甲酸钙实验的安全性进行了分析,并根据分析结果提出了对策及相应的安全规程。The method using calcium carbide residue and carbon monoxide as raw materials to prepare calcium formate through the carbonylation synthesis route has become a research hot spot in China.However this experiment has great risk,because the reaction raw material CO is a flammable,explosive,toxic chemi-cal,and at the same time this reaction also requires high temperature,high pressure conditions.Therefore, before the experiments begin,the system safety must be carefully analyzed to develop appropriate safety oper-ation procedures.In this paper,the safety of test tank reactor devices are analyzed,the safety operation pro-cedures are proposed according to the analysis results.

关 键 词：系统安全分析 安全操作规程 危险化学品 一氧化碳 应急预案 

分 类 号：TQ086[化学工程]