Selective adsorption of metronidazole on conjugated microporous polymers  

作　　者：Chunli Zheng Miaomiao Du Fei Li Yue Qi Jun Yi 

机构地区：[1]Department of Environmental Science and Engineering,Xi'an Jiaotong University [2]Department of Chemistry,School of Sciences,Xi'an Jiaotong University [3]Henan Research Academy of Environmental Sciences

出　　处：《Science China Chemistry》2015年第7期1227-1234,共8页中国科学（化学英文版）

基　　金：supported by the National Natural Science Foundation of China(21307097,21105079);Industrial Research Project of Science and Technology Department of Shaanxi Province(2014K10-02,2012K08-18);the Fundamental Research Funds for the Central Universities(2012jdhz39);the Key Laboratory of Industrial Ecology and Environmental Engineering,Ministry of Education of China

摘　　要：Conjugated microporous polymers(CMPs) have recently received extensive attention in oil/organic solvent-water separation field as a kind of ideal porous absorbents with tunable porosity, large surface areas, and super-hydrophobicity. However, reports on the application of CMPs in adsorption of hydrophilic contaminants from water are very few. In this work, we studied the adsorption of metronidazole(MNZ), a polar antibiotic, by two kinds of CMPs. The adsorption characteristics of MNZ by the CMPs, including adsorption kinetics, mechanism, and isotherm parameters were calculated. The adsorption kinetics of MNZ was well expressed by the pseudo-second-order model, and the adsorption process was found to be mainly controlled by film diffusion. The adsorption isotherm data agreed well with the Langmuir isotherm model, and the values of free energy E indicated that the adsorption nature of MNZ on the CMPs was physisorption. Increasing dispersion degree of the CMPs in MNZ solution resulted in greater adsorption. This work may provide fundamental guidance for the removal of antibiotics by CMPs.Conjugated microporous polymers （CMPs） have recently received extensive attention in oil/organic solvent-water separation field as a kind of ideal porous absorbents with tunable porosity, large surface areas, and super-hydrophobicity. However, re- ports on the application of CMPs in adsorption of hydrophilic contaminants from water are very few. In this work, we studied the adsorption of metronidazole （MNZ）, a polar antibiotic, by two kinds of CMPs. The adsorption characteristics of MNZ by the CMPs, including adsorption kinetics, mechanism, and isotherm parameters were calculated. The adsorption kinetics of MNZ was well expressed by the pseudo-second-order model, and the adsorption process was found to be mainly controlled by film diffusion. The adsorption isotherm data agreed well with the Langmuir isotherm model, and the values of free energy E indicated that the adsorption nature of MNZ on the CMPs was physisorption. Increasing dispersion degree of the CMPs in MNZ solution resulted in greater adsorption. This work may provide fundamental guidance for the removal of antibiotics by CMPs.

关 键 词：conjugated microporous polymer METRONIDAZOLE ADSORPTION HYDROPHOBICITY 

分 类 号：O647.3[理学—物理化学]