基于邻菲啰啉的Cu(Ⅱ)混配配合物的合成与表征  

Synthesis and characterization of Cu(Ⅱ) mixed complex with phenanthroline

作　　者：张翠荣[1] 李明[2] 李荣玉[2] 张承[2] 韩晶波[2] 高强[1] 侯少锋[2] 

机构地区：[1]贵州大学精细化工研究开发中心,贵州贵阳550025 [2]贵州大学作物保护研究所,贵州贵阳550025

出　　处：《贵州师范大学学报（自然科学版）》2015年第3期92-95,共4页Journal of Guizhou Normal University：Natural Sciences

基　　金：公益性行业(农业)科研专项经费项目(201203038-08)

摘　　要：先合成2-巯基-4,6-二甲基嘧啶配体,再与邻菲啰啉及硝酸铜利用水热反应,合成了铜(II)的固态配合物,并通过红外光谱分析、紫外光谱分析、荧光光谱分析和滴定分析等技术手段,进一步推测该配合物的可能组成。The ligand of 2-mercapto-4,6-dimethyl-pyrimidine was first synthesized. And its solid complex with Cu （Ⅱ） was prepared for phenanthroline and eopper nitrate with hydrothermal reaction ket- tle. The ligand and its complex were characterized by IR spectrum, UV spectrum, fluorescent spectrum, and the content of the Cu （Ⅱ） was determined by titration. Their possible component of the complex was guessed from above analysis.

关 键 词：2-巯基-4 6-二甲基嘧啶 邻菲啰啉 铜(Ⅱ)配合物 

分 类 号：O614.121[理学—无机化学]