CuO-ZnO/Al_2O_3双功能催化剂上纤维素催化液化:焙烧温度的影响  

Catalytic liquefaction of cellulose over CuO-ZnO/Al_2O_3 bi-functional catalyst: Effect of calcination temperature

作　　者：陈新怡[1,2] 马清龙 包桂蓉[1,2] 李法社[1,2] 李秀凤[2] 

机构地区：[1]昆明理工大学省部共建复杂有色金属资源清洁利用国家重点实验室,云南昆明650093 [2]昆明理工大学冶金与能源工程学院,云南昆明650093

出　　处：《应用化工》2015年第6期1012-1015,1020,共5页Applied Chemical Industry

基　　金：国家自然科学基金(51266003)

摘　　要：采用共沉淀法制备了一系列不同焙烧温度用于超临界甲醇中催化液化纤维素的CuO-ZnO/Al2O3催化剂。运用XRD、TG/DTG、BET和H2-TPR等手段对催化剂进行表征与分析,考察了焙烧温度对CuO-ZnO/Al2O3催化剂结构及催化性能的影响。结果表明,500℃焙烧下的催化剂,热分解较为完全,CuO、ZnO和Zn Al2O4之间相互作用良好且结构稳定,反应活性较高。当焙烧温度<500℃,催化剂结晶效果差,稳定性差,导致催化剂活性低;当焙烧温度>500℃时,CuO因为高温发生团聚,生成的大量尖晶石Zn Al2O4使催化剂组分相互作用削弱。在300℃、60 mg微晶纤维素,60 mg催化剂,3 m L甲醇反应60 min条件下进行液化试验及重复性研究,500℃焙烧催化剂表现出良好的活性和稳定性。A series of CuO-ZnO/Al2O3 catalysts were prepared using catalyst liquefaction of cellulose in supercritical methanol which was synthesized by the co-precipitation method at various calcination temperatures. The effect of the different calcination temperature on catalyst structure and performance was investigated by using XRD,TG/DTG,BET,H2-TPR. The results showed that CuO-ZnO/Al2O3 catalysts was almost completely decomposed at 500 ℃. It has a good stability,activity because of the excellent proper force between CuO,ZnO and Zn Al2O4. Poor crystallization and stability were the reasons which lead to the decrease of the catalyst activity when the calcination temperature is less than 500 ℃. Higher calcination temperature（ 500 ℃） resulted in the agglomeration of CuO,generated a large number of Zn Al2O4 make catalyst component interaction. The catalyst calcined at 500 ℃ showed good activity and stability for the repeatability test at the conditions of 300 ℃,cellulose 60 mg,60 mg catalyst,3 m L methanol and holding time 60 min.

关 键 词：CuO-ZnO/Al2O3 焙烧温度 超临界甲醇 纤维素 催化液化 

分 类 号：TQ530.24[化学工程—煤化学工程]