Bi(Mg_(1/2)Ti_(1/2))O_3-PbTiO_3压电陶瓷体系介电与居里温度特性研究  

Dielectric properties and high Curie temperature of Bi(Mg_(1/2)Ti_(1/2))O_3-PbTiO_3 ceramics

作　　者：张强[1] 李振荣[2] 

机构地区：[1]西安建筑科技大学功能材料研究所,西安710055 [2]西安交通大学国际电介质中心,西安710049

出　　处：《功能材料》2015年第13期13057-13061,共5页Journal of Functional Materials

基　　金：陕西省教育厅自然科学基金资助项目(2013JK0924);陕西省科技厅青年人才资助项目(2015JQ5168);西安建筑科技大学人才基金资助项目(RC1434)

摘　　要：采用传统固相法工艺制备了（1-x ）Bi （Mg1/2 Ti1/2 ）O3-xPbTiO3 （BMT-xPT,0.34≤x ≤0.44）陶瓷.研究发现,随着PT含量增加,试样结构由三方相逐渐转变为四方相结构,当0.36〈x〈0.40时,试样结构处于准同型相界（MPB）区.研究表明BMT组元是一种具有非铁电体特征的组分,随着PT 含量减少,BMTGPT体系的居里温度减小,介电峰变得越来越不明显.通过研究BMT-PT 体系组分与居里温度（TC）的关系可以看出：（1）PT 含量为0.34-0.44时,TC 随BMT含量变化实验值和Stringer的经验值差异较小,变化趋势一致;（2）BMTGPT体系居里温度最大值可能在x =0.73 的附近,其居里温度最大值TCmax约为550℃.( 1- x) Bi( Mg1 /2Ti1 /2) O3-x Pb Ti O3( BMT-x PT,0. 34≤x≤0. 44) ceramics were prepared by conventional powder-processing method. With PT content increasing,a phase transition from the rhombohedral phases to tetragonal phases was observed,and when PT content was between 0. 36 and 0. 40,the morphotropic phase boundary( MPB) composition was investigated. With PT content decreasing,the value of TCwas deceasing; meanwhile the dielectric peak becomes unobvious,indicating that BMT was not a ferroelectrics composition. Finally,it can be found that the change of experimental value was accord with the value of Stringer's report for 0. 34≤x≤0. 44. Thus,it can infer that the maximum TCwas around x = 0. 73 for BMT-x PT system,which was about 550 ℃

关 键 词：压电陶瓷 居里温度 介电性能 准同型相界 

分 类 号：TM282[一般工业技术—材料科学与工程]