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出 处:《合成橡胶工业》2015年第4期258-262,共5页China Synthetic Rubber Industry
摘 要:综述了近年来美国Akron大学在橡胶合成机理与合成方法方面所做的研究工作,分别介绍了聚异丁烯、聚苯乙烯和聚异戊二烯类橡胶的制备、理化性能及可能的应用领域,并对合成这些橡胶所涉及的聚合反应及聚合机理进行了说明,对聚合机理的研究方法也有所提及,同时介绍了一些新型聚合反应引发剂或引发体系及其在橡胶合成和改性方面的应用。Advances in the researches of mechanisms and methods of rubber synthesis were reviewed of Akron University in recent years. Preparation, physical and chemical properties and possible applications of polyisobutene, polystyrene and polyisoprene rubbers were introduced respectively, and their corresponding polymerization reactions andmechanisms were illustrated with 22 references. The approaches to polymerization mechanisms were involved, and some novel initiators or initiating systems and their applications in the synthesis and modification of rubbers were introduced as well.
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