液相色谱-串联质谱法测定纺织品中克莱范  

Determination of kelevan in textiles with LC-MS/MS method

作　　者：陈山丹[1] 费桂琴[1] 李敬[1] 蔡建和 

机构地区：[1]江苏出入境检验检疫局轻工产品与儿童用品检测中心,江苏扬州225009 [2]江苏省检验检疫科学技术研究院,江苏南京210001

出　　处：《印染》2015年第14期48-50,共3页China Dyeing and Finishing

基　　金：质检公益性行业科研专项(201310059)

摘　　要：采用液相色谱-串联质谱法测定纺织品中克莱范。试样用甲醇萃取过滤后,采用液质联用仪对其进行定性定量分析。流动相为甲醇/乙酸铵,梯度分析。采用高流速电喷雾离子源(HESI),定性离子对为633.8/426.8;定量子离子为633.8/587.8。添加质量分数为2.5~50.0μg/kg时,回收率为88%~102%,相对标准偏差为5.04%~9.01%,检出限为0.19μg/kg。The determination of kelevan in textiles by liquid chromatography-tandem mass spectrometry （LC-MS/MS） is introduced. Test sample is extracted with methanol, and analyzed by LC-MS/MS after filtration. Gradient analysis is used with methanol/ammonium as mobile phase. High velocity electro-spray ionization source is applied. The qualitative ion pair is 633.8/426.8 and the quantitative ion pair is 633.8/ 587.8. While the concentration is 2.5-50.0 t^g/kg, the recovery rates are 88%-102%, the RSDs are 5.04%- 9.01% and the limit of determination is 0.19 μg/kg.

关 键 词：测试 液相色谱法 串联质谱法 克莱范 纺织品 

分 类 号：O657.63[理学—分析化学] TS107[理学—化学]