燃煤电厂脱硝工艺对其粉煤灰性质的影响  

Effect of Denitration in Thermal Power Plant on Properties of Fly Ash

作　　者：张宇[1] 王智[1,2] 王子仪[1] 孙化强[2] 王林龙[2] 文成明[3] 张泳涛 唐中德 

机构地区：[1]重庆大学化学化工学院,重庆400044 [2]重庆大学材料科学与工程学院,重庆400045 [3]华能重庆珞璜发电有限责任公司,重庆402283 [4]重庆华珞粉煤灰开发有限责任公司,重庆404000

出　　处：《非金属矿》2015年第4期9-12,共4页Non-Metallic Mines

基　　金：国家科技支撑项目(2011BAA04B04);华能国际电力科技项目

摘　　要：脱硝是治理燃煤产生NOx污染的重要技术手段,为了提高脱硝后粉煤灰的建材资源化利用水平,以脱硝与未脱硝粉煤灰为研究对象,利用水泥化学分析方法、XRD分析仪和激光粒度仪等手段研究其化学组成、矿物组成和粒径分布等基本性质的变化规律,并分析了脱硝后含氮物质在粉煤灰中的含量和存在形式。结果表明,正常脱硝工况下,粉煤灰粒径较脱硝之前有所增大,而对化学组成、矿物组成、p H值和需水量比等性质几乎无影响;脱硝后的粉煤灰强度活性指数较未脱硝降低不明显,脱硝对火山灰活性影响很小;脱硝后粉煤灰中含氮物质主要为粉煤灰吸附的脱硝剂NH3和残留脱硝副产物NH4HSO4、(NH4)2SO4,其量与反应器氨逃逸水平和SO2浓度有关。The denitration is a significant means of controlling NOx pollution, to improve level of building materials recycling and using stability of fly ash after denitration. The fly ash before and after denitration were as objects of study. The chemical composition, mineral composition and artical size were studied and analyzed by Cement chemical analysis method, XRD diffraction analyzer and Mastersizer.The form and content of ammonium salt from fly ash after denitration were focused on. The research results indicate that the partical size of fly ash after denitration increase a little under normal working condition of denitration,but chemical composition, mineral composition and p H has not been influenced and water demand ratio has not changed. The strength activity index of fly ash after denitration decrease little. The effect of denitration on pozzolanic activity of fly ash is very little.There are NH3,（NH4）2SO4 and NH4HSO4 in fly ash after denitration.And the content are connected with ammonia escape level and density of SO2 of reactor.

关 键 词：脱硝工艺 粉煤灰 性质 火山灰活性 

分 类 号：X773[环境科学与工程—环境工程]