烯烃二胺化反应制备邻二胺化合物的研究进展  

Development of Direct Vicinal Diamination of Alkenes

作　　者：李亚妮[1] 王为强[1] 余秦伟[1] 梅苏宁[1] 王伟[1] 张前[1] 杨建明[1] 吕剑[1] 

机构地区：[1]西安近代化学研究所,西安710065

出　　处：《化学通报》2015年第7期597-601,共5页Chemistry

摘　　要：介绍了通过烯烃二胺化反应路线制备邻二胺化合物的研究工作,对烯烃二胺化反应的类型及催化体系进行了综述,钯、铜金属催化剂及超价碘(Ⅲ)试剂对烯烃二胺化反应具有普适性,环境友好的铜及非金属催化剂是未来研究的热点。The research work in direct diamination of alkenes to vicinal diamines was introduced and various reaction types and catalysts of diamination of alkenes were reviewed. Palladium catalyst and copper catalyst or hypervalent iodine （III） presented the broad applicability on diamination of alkenes, respectively. Environment friendly copper catalyst and metal-free catalysts will attract more attention in the future.

关 键 词：烯烃 邻二胺 分子内二胺化 分子间二胺化 催化剂 

分 类 号：TQ226.31[化学工程—有机化工]