Iron-catalyzed aerobic oxidative amidation of tertiary amines with carboxylic acids  

作　　者：Lina Ma Yuanming Li Zhiping Li 

机构地区：[1]Department of Chemistry, Renmin University of China

出　　处：《Science China Chemistry》2015年第8期1310-1315,共6页中国科学（化学英文版）

基　　金：financially supported by the Fundamental Research Funds for the Central Universities;the Research Funds of Renmin University of China(10XNL017)

摘　　要：An oxidative amidation of tertiary amines with carboxylic acids has been developed in the presence of FeC13- 6H20 as catalyst and oxygen as oxidant. A variety of tertiary amides were obtained in good to excellent yields from inexpensive and readily available reagents. The possible reaction pathways were investigated.An oxidative amidation of tertiary amines with carboxylic acids has been developed in the presence of Fe Cl3·6H2O as catalyst and oxygen as oxidant.A variety of tertiary amides were obtained in good to excellent yields from inexpensive and readily available reagents.The possible reaction pathways were investigated.

关 键 词：AMIDATION tertiary amine carboxylic acid iron catalysis OXIDATION 

分 类 号：O621.25[理学—有机化学]