Copper-catalyzed arenes amination with saccharins  

作　　者：Kai Sun Yan Li Qian Zhang 

机构地区：[1]College of Chemistry and Chemical Engineering, Anyang Normal University [2]Department of Chemistry, Northeast Normal University

出　　处：《Science China Chemistry》2015年第8期1354-1358,共5页中国科学（化学英文版）

基　　金：financially supported by the National Natural Science Foundation of China(21172033,21372041,21302017)

摘　　要：A novel copper-catalyzed direct C–N formation reaction of simple arenes with cheap and pharmacological saccharin derivatives under relatively mild conditions was developed with arenes as limiting reagents.This work provided a new method for oxidative coupling of aromatic C(sp2)–H bonds and N–H bonds.A novel copper-catalyzed direct C-N formation reaction of simple arenes with cheap and pharmacological saccharin deriva- tives under relatively mild conditions was developed with arenes as limiting reagents. This work provided a new method for oxidative coupling of aromatic C（sp2）-H bonds and N-H bonds.

关 键 词：aromatic amines C-N bond formation ARENES saccharins arenes as limiting reagents 

分 类 号：O621.25[理学—有机化学]