若干功能体系的定向设计与构筑  

Rational design and construction of several functional systems

作　　者：李激扬[1] 王栋[2] 王远[3] 杜红宾[4] 邓亮[5] 侯雪龙[5] 于吉红[1] 

机构地区：[1]吉林大学无机合成与制备化学国家重点实验室,长春130012 [2]中国科学院化学研究所,北京100190 [3]北京大学化学与分子工程学院,分子动态与稳态结构国家重点实验室,北京100871 [4]南京大学配位化学国家重点实验室,南京210093 [5]中国科学院上海有机化学研究所,金属有机化学国家重点实验室,上海200032

出　　处：《科学通报》2015年第21期1987-1991,共5页Chinese Science Bulletin

基　　金：国家重点基础研究发展计划(2011CB808700)资助

摘　　要：本项目基于"分子工程学"思想,以功能为导向,在分子水平上对结构进行设计与剪裁,最终实现特定功能体系(分子基体系、表界面体系、多孔体系、配合物体系、金属有机体系及分子反应体系)的定向合成、制备与组装.在分子自组装,表界面及能级结构的调控,多孔空间结构的设计构筑与合成规律,金属价态、基元构型、边臂协助的作用机制,化学键的可控断裂与形成等方面取得一些新进展,为促进化学以及环境、能源、材料及生命等领域的迅速发展提供科学基础.This program is based on the idea of ＂molecular engineering＂, that is, function-oriented design and tailor of structures at the molecular level, and ultimately to achieve the rational synthesis, preparation, and assembly of specific functional systems. A number of functional systems including the molecular-based system, surface and interface system, porous system, complex system, metal organic system and molecule-based system, have been selected in this study. Some progresses have been achieved in the aspects of molecule selfassembly, chemical regulation of surface-interface and energy-level structure, designed construction and synthesis of porous materials, mechanism of metal valence, elementary configuration and side-arm assistance, as well as controllable breaking and forming of chemical bonds. The implementation of the project will lay scientific fundations to advance the developments of chemistry, environment, energy, materials and life science, etc.

关 键 词：分子工程学 表界面 多孔材料 共价键 光电 催化 

分 类 号：O641[理学—物理化学]