环境响应型螺噁嗪类化合物合成研究进展  

Research Progress on Preparation of Environmental Response Type of Spirooxazine Compounds

作　　者：刘波[1] 周小楚 吕维忠[1] 

机构地区：[1]深圳大学化学与化工学院,广东深圳518060

出　　处：《广州化工》2015年第15期5-6,19,共3页GuangZhou Chemical Industry

基　　金：国家国际科技合作专项项目(2013DFG52970);深圳市科技计划项目(JCYJ20140418193546109;JCYJ20140509135949790);南山区创新研发资助项目(KC2013JSCX0015A);深圳大学南山区工业技术研究院资助项目

摘　　要：螺噁嗪是一类重要的有机光致变色化合物,具有较高的化学稳定性、抗光疲劳性和光敏性,可根据环境中光谱的变化而发生变色反应,在建筑和汽车玻璃等多个领域具有广泛的应用。从螺噁嗪类化合物的基本合成思路出发,本文主要综述环境响应型单螺噁嗪类化合物、环境响应型双螺嗪类化合物及环境响应型螺噁嗪聚合物合成的方法,讨论了环境响应型螺噁嗪母环结构对于光致变色性质的影响,介绍了微波合成手段在环境响应型螺噁嗪类化合物合成中的应用,对其在合成方面重点研究的方向讨论并进行了展望。As an important class of organic photochromic compounds, spirooxazine has a high chemical stability, photosensitivity and fatigue resistance to light, which can change color according to the changing environment in the spectral response, so it is also called environmental responses compounds in many areas, such as construction and automotive, spirooxazine compounds have wide application.In order to obtain better performance environment responsive spirooxazine compounds, they were designed and synthesized as a hot research.Staring with the review of the basic idea spirooxazine synthetic compounds, synthesis of spirooxazine of single compound, double spirooxazine spirooxazine compounds and polymers was studied, the environment-responsive spirooxazine parent ring structure of light-induced impact of color in nature was discussed, the application of microwave, ultrasound and other applications in the synthesis of compounds spirooxazine class were described and spirooxazine compounds in the synthesis of key research directions were discussed too.

关 键 词：螺噁嗪类化合物 环境响应型 光致变色 合成研究 

分 类 号：O62[理学—有机化学]