SBA-15锚定Cu(Ⅱ)-DiAmSar配合物催化剂上无溶剂高效合成吡啶并吡嗪和喹喔啉衍生物（英文）  

Efficient solvent-free synthesis of pyridopyrazine and quinoxaline derivatives using copper-DiAmSar complex anchored on SBA-15 as a reusable catalyst

作　　者：Marzieh Mohammadi Ghasem Rezanejade Bardajee Nader Noroozi Pesyan 

机构地区：[1]Department of Chemistry, Faculty of Science, Urmia University, 57159, Urmia, Iran [2]Department of Chemistry, Payame Noor University, P.O. BOX, 19395-3697, Tehran, Iran

出　　处：《催化学报》2015年第8期1379-1386,共8页

基　　金：supported by Payame Noor University

摘　　要：A catalytic system comprising mesoporous silica functionalized with Cu(II)-DiAmSar was synthesized. This was demonstrated as an efficient heterogeneous catalyst for the synthesis of biologically useful pyridopyrazine and quinoxaline heterocycles under solvent-free conditions. X-ray diffraction, transmission electron microscopy, N2 adsorption-desorption, Fourtier transformation infrared spectroscopy, and thermogravimetric analysis were used to characterize the catalyst and investigate the texture of SBA-15 during the grafting process.A catalytic system comprising mesoporous silica functionalized with Cu（II）-DiAmSar was synthesized. This was demonstrated as an efficient heterogeneous catalyst for the synthesis of biologically useful pyridopyrazine and quinoxaline heterocycles under solvent-free conditions. X-ray diffraction, transmission electron microscopy, N2 adsorption-desorption, Fourtier transformation infrared spectroscopy, and thermogravimetric analysis were used to characterize the catalyst and investigate the texture of SBA-15 during the grafting process.

关 键 词：SBA-15 无溶剂合成 催化剂 衍生物 喹喔啉 吡嗪 吡啶 可回收 

分 类 号：O626[理学—有机化学]