刺激响应性聚合物的设计、合成及其应用研究新进展  

New progress in the design,synthesis and application of stimuli responsive polymers

作　　者：杨倩丽[1,2] 康晓明[1] 孙静[1] 魏柳荷[1] 马志[2] 

机构地区：[1]郑州市弹性密封材料重点实验室,郑州大学化学与分子工程学院,河南郑州450052 [2]中国科学院有机功能分子合成与组装化学重点实验室,中国科学院上海有机化学研究所,上海200032

出　　处：《化工进展》2015年第8期3075-3084,3098,共11页Chemical Industry and Engineering Progress

基　　金：国家自然科学基金项目(21074146,21374130)

摘　　要：介绍了研究刺激响应性聚合物的意义,针对水体系中的刺激响应性聚合物,介绍了近年来刺激响应性聚合物的设计与合成中的应用研究新进展,主要从3个方面进行阐述:1单一刺激响应性聚合物,包括温度、p H值、光、其他刺激响应性聚合物;2双重刺激响应性聚合物,包括温度-p H值、温度-光、温度-氧化还原刺激响应聚合物、p H值-氧化还原刺激响应聚合物;3多重刺激响应性聚合物,包括温度-光-p H值、温度-光-氧化还原、温度-p H值-CO2刺激响应聚合物。着重评述了水体系中双重和多重刺激响应性聚合物的合成研究及应用。最后总结了多重刺激响应性聚合物应用研究的现状及问题,指出开发刺激响应性高度可控、灵敏度高、可逆性好的新型多重刺激响应性聚合物是未来的研究方向。This review first describes the general significance of the study on stimuli-responsive polymers. Then the latest research progress in the design, synthesis and application of stimuli-responsive polymers in aqueous solution is reviewed. Three kinds of stimuli-responsive polymers are introduced： 1 single stimuli-responsive polymers： temperature, pH, light and other single stimuli-responsive polymers. 2 dual stimuli-responsive polymers： temperature/pH, temperature/light and temperature/redox stimuli-responsive polymers.3multiple stimuli-responsive polymers： temperature/light/pH, temperature/light/redox and temperature/pH/CO2 stimuli-responsive polymers. In addition, the dual and multiple stimuli-responsive polymers are intensively reviewed. At last, the current situation and problems of multiple stimuli-responsive polymers are summarized, and the development of multiple stimulus responsive polymers with high sensitivity, high sensitivity and good reversikility will be the future development directions.

关 键 词：刺激响应性 设计与合成 聚合物 聚合 水溶液 

分 类 号：O632.1[理学—高分子化学] TQ325[理学—化学]