蜡油加氢裂化工艺中金刚烷指纹化合物的分析及应用  

Analysis and Application of Diamondoid Fingerprints in Hydrocracking of Vacuum Gas Oils

作　　者：陈菲[1] 刘颖荣[1] 蔡新恒 田松柏[1] 赵阳[1] 

机构地区：[1]中国石化石油化工科学研究院,北京100083

出　　处：《石油学报（石油加工）》2015年第4期953-958,共6页Acta Petrolei Sinica(Petroleum Processing Section)

基　　金：国家重点基础研究发展规划"973"项目(2012CB224800)资助

摘　　要：选择单金刚烷及双金刚烷化合物作为烃指纹化合物,采用气相色谱/质谱（GC/MS）对其进行定性及定量分析,考察了不同加氢裂化条件下,金刚烷化合物的含量及其分布特点。结果表明,减压蜡油（VGO）经加氢裂化后,165~350℃中间馏分产品中存在丰富的金刚烷化合物;随着转化率的增加,双金刚类烷化合物含量均不断增加,而部分单金刚烷类化合物在高转化率条件下含量减少。在加氢裂化过程中,金刚烷化合物含量变化与烃类组成的变化密切相关,并且金刚烷化合物指纹参数与加氢裂化反应转化率呈现良好的线性关系,可监测加氢裂化反应深度及烃类变化。Diamondoid, the rigid, three-dimensionally fused cyclonexyi-ring alkane cumpoundsare widely found in crude oils and refined products, which are much more stable than other hydrocarbons in the hydroeracking process, so they were chosen as fingerprinting compounds used in hydrocracking process. Their distributions were examined by GC/MS in the various midrange products with different conversion rates. It was found that the mass fraction of adamatanes decreased gradually under the high conversion rate, which was closely related to other hydrocarbons in the process. The indices of diamantanes had a good linear relation with the conversion rate of hydrocracking process, implying that the diamonoid compounds were of certain indicating significance for the change of other hydrocarbons to some extent.

关 键 词：金刚烷 GC/MS 加氢裂化 转化率 烃指纹化合物 

分 类 号：TE622[石油与天然气工程—油气加工工程]