Experimental Binary Phase Diagram of Bilayer Compounds [n-CnH2n＋1N（CH3）3]2CoCl4  

作　　者：WU Kezhong SUN Xiaolong RUAN Bei XIONG Yuanyuan CHEN Jing 

机构地区：[1]Department of Chemistry and Material Science, Hebei Normal University, Shijiazhuang 050024, P tL China

出　　处：《Chemical Research in Chinese Universities》2015年第4期611-614,共4页高等学校化学研究（英文版）

基　　金：Supported by the National Natural Science Foundation of China（Nos.21473048, 21246006）, the Natural Science Foundation of Hcbci Province, China（No.B2012205034） and the Science Foundation of Hebci Normal University, China（Nos.L2011K04, L2013B07）.

摘　　要：Compounds [n-CnH2n＋1N（CHs）3]2CoCl4（n=16, C46C3Co; n=18, C18C3Co） containing lipid-like bilayers embedded in a crystalline matrix exist in solid-solid phase transition. The low-temperature bilayer structures of the two compounds were organized by neutralizing CoCl24- with alkylammonium ions. Alkyl chains lay parallel to each other and slightly tilted with respect to the normal of the inorganic layers. The adjacent alkyl chains interacted with each other by van der Waals interaction. When the temperature increased, the two compounds underwent a reversible solid-solid phase transformation within 310-330 K. In such a case, the chains showed a large motional freedom, and a disordered phase appeared. The structures can alternatively be viewed as a double layer of alkylammonium ions between COCl24- sheets and be considered as crystalline models of lipid bilayers. The experimental subsolidus binary phase diagram of [n-C16H33N（CH3）3]2CoCl4-[n-C18H37N（CH3）3]2CoCl4 was constructed over the entire composition range by differential scanning calorimetry and X-ray diffraction technique. Experimental phase diagram indicates one stable intermediate phase [n-C16H33N（CH3）3][n-C18H37N（CH3）3]CoCl4 at wC16C3Co = 39.89% and two invariant three-phase equilibria, which shows two eutectoid temperatures： Te1 at （316±1） K for WC16C3Co=27.35% and Te2 at （313±1）K for Wc16c3co =59.76%. These three noticeable solid-solution ranges are a-phase at the left, β-phase at the right, and γ-phase in the middle of the phase diagram.Compounds [n-CnH2n＋1N（CHs）3]2CoCl4（n=16, C46C3Co; n=18, C18C3Co） containing lipid-like bilayers embedded in a crystalline matrix exist in solid-solid phase transition. The low-temperature bilayer structures of the two compounds were organized by neutralizing CoCl24- with alkylammonium ions. Alkyl chains lay parallel to each other and slightly tilted with respect to the normal of the inorganic layers. The adjacent alkyl chains interacted with each other by van der Waals interaction. When the temperature increased, the two compounds underwent a reversible solid-solid phase transformation within 310-330 K. In such a case, the chains showed a large motional freedom, and a disordered phase appeared. The structures can alternatively be viewed as a double layer of alkylammonium ions between COCl24- sheets and be considered as crystalline models of lipid bilayers. The experimental subsolidus binary phase diagram of [n-C16H33N（CH3）3]2CoCl4-[n-C18H37N（CH3）3]2CoCl4 was constructed over the entire composition range by differential scanning calorimetry and X-ray diffraction technique. Experimental phase diagram indicates one stable intermediate phase [n-C16H33N（CH3）3][n-C18H37N（CH3）3]CoCl4 at wC16C3Co = 39.89% and two invariant three-phase equilibria, which shows two eutectoid temperatures： Te1 at （316±1） K for WC16C3Co=27.35% and Te2 at （313±1）K for Wc16c3co =59.76%. These three noticeable solid-solution ranges are a-phase at the left, β-phase at the right, and γ-phase in the middle of the phase diagram.

关 键 词：Quaternary ammonium tetrachlorometallate Differential scanning calorimetry Eutectoid temperature Phase equilibrium Phase diagram 

分 类 号：O642[理学—物理化学] O641.3[理学—化学]