Variation of temporal and spatial patterns of NO_2 in Beijing using OMI and mobile DOAS  

作　　者：Ang Li Jie Zhang Pinhua Xie Zhaokun Hu Jin Xu Fusheng Mou Fengcheng Wu Jianguo Liu Wenqing Liu 

机构地区：[1]Key Laboratory of Environmental Optical and Technology [2]Anhui Institute of Optics and Fine Mechanics, Chinese Academy of Sciences [3]School of Environmental and Photoelectric Technology, University of Science and Technology of China

出　　处：《Science China Chemistry》2015年第9期1367-1376,共10页中国科学（化学英文版）

基　　金：supported by the National Natural Science Foundation of China(41275038);the Key Research Program of the Chinese Academy of Sciences(KJZD-EW-TZ-G06);the National High Technology Research and Development Program of China(2014AA06A508,2014AA06A511);the Scientific and Technological Project of Anhui Province(1301022083);the Special Project of Environmental Nonprofit Industry Research,China(201409006)

摘　　要：Control policies such as "odd-and-even license plate rule" were implemented by the Chinese government to restrict traffic and suspend factory production in Beijing and neighboring cities during the Asia-Pacific Economic Cooperation summit. We use ozone monitoring instrument(OMI), mobile differential optical absorption spectroscopy(DOAS), and multi-axis differential optical absorption spectroscopy(MAX-DOAS) to measure the variation of the spatial and temporal patterns of NO2 column densities from October 24, 2014 to November 22, 2014. It is found that the NO2 column densities during the episode of control policies are significantly lower than those during other periods, and the emission flux of NO2 calculated by mobile DOAS is also lower than the results from other periods. Some daily low NO2 column densities occur with the northwest wind direction. We then compare the relationship between OMI and mobile DOAS NO2 column density observations, and the results of mobile DOAS are approximately 2.7 times larger than the OMI values. The largest discrepancy occurs in the northern part of Beijing city. In other parts, the two instruments have a better correlation coefficient(R2) of 0.61. The low NO2 column densities that occur during the episode of control policies are affected by the control policies as well as meteorological conditions.Control policies such as ＂odd-and-even license plate rule＂ were implemented by the Chinese government to restrict traffic and suspend factory production in Beijing and neighboring cities during the Asia-Pacific Economic Cooperation summit. We use ozone monitoring instrument（OMI）, mobile differential optical absorption spectroscopy（DOAS）, and multi-axis differential optical absorption spectroscopy（MAX-DOAS） to measure the variation of the spatial and temporal patterns of NO2 column densities from October 24, 2014 to November 22, 2014. It is found that the NO2 column densities during the episode of control policies are significantly lower than those during other periods, and the emission flux of NO2 calculated by mobile DOAS is also lower than the results from other periods. Some daily low NO2 column densities occur with the northwest wind direction. We then compare the relationship between OMI and mobile DOAS NO2 column density observations, and the results of mobile DOAS are approximately 2.7 times larger than the OMI values. The largest discrepancy occurs in the northern part of Beijing city. In other parts, the two instruments have a better correlation coefficient（R2） of 0.61. The low NO2 column densities that occur during the episode of control policies are affected by the control policies as well as meteorological conditions.

关 键 词：OMI DOAS NO2 emission flux control policies 

分 类 号：X87[环境科学与工程—环境工程] X831