Y_2O_3:Eu空心球的合成及其发光性能研究  

Y2O3: Eu Hollow Submicrospheres: Preparation and Photoluminescence Properties

作　　者：赵永霞[1] 聂志文[1] 石孟孟 廖媛媛[1] 王雷[1] 钟声亮[1] 

机构地区：[1]江西师范大学化学化工学院,江西南昌330022

出　　处：《江西师范大学学报（自然科学版）》2015年第4期415-419,共5页Journal of Jiangxi Normal University(Natural Science Edition)

基　　金：国家自然科学基金(21201089;21261010;61201104);江西省教育厅科技落地计划(GJJ11382);江西省科技厅青年科学家培养对象(20144BCB23039)资助项目

摘　　要：以吡啶-2,5-二羧酸为配体,通过简单的混合溶剂热法制备了铕离子掺杂的钇基配位聚合物超微球,其粒径约为350 nm.在800℃煅烧4 h后得到了Y2O3:Eu空心超微球.用SEM、TEM、XRD等方法对合成的产物进行了表征.此外,对掺杂不同浓度Eu3+的Y2O3:Eu空心超微球的发光性能进行了研究.结果表明:当掺杂铕的摩尔分数为5%时,其发光强度最强.In this work,Eu^3＋-doped yttrium-based coordination polymer ultramicroballoon with diameters of about350 nm have been successfully synthesized employing 2,5-pyridinedicarboxylic acid as ligand by a simple mixedsolvothermal route. Y2O3： Eu hollow submicrospheres were obtained after thermolysis of the precursors at 800 ℃ for4 h. The as-prepared products were characterized by scanning electron microscope（ SEM）,transmission electron microscopy（ TEM） and X-ray powder diffraction（ XRD）. In addition,the luminescent properties of Y2O3： Eu by varying the doping concentration of Eu^3＋ were studied. The results show that when the doping concentration of Eu^3＋ is 5%,the luminescent properties of Y2O3： Eu is the strongest.

关 键 词：Y2O3:Eu 配位聚合物 空心球 混合溶剂热 

分 类 号：O611.4[理学—无机化学]