Regioselective Oxidation Approaches to Concise Synthesis of （±）-Canabisin D  

作　　者：Wenling Li Qian Liu Hao Liu PeUan Chen Xi Yang Yingying Liu 

机构地区：[1]School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou, Gansu 730070, China

出　　处：《Chinese Journal of Chemistry》2015年第7期717-722,共6页中国化学（英文版）

基　　金：This research work was financially supported by the National Natural Science Foundation of China （No. 21462024） and the Scientific Research Foundation for the Returned Overseas Chinese Scholars of State Education Ministry （2013）.

摘　　要：The regioselective effects of tert-butyl or bromine as the position-protecting group of feruloytyamide on the oxidative coupling reactions for the synthesis of natural （±）-canabisin D were investigated in detail. The coupling yield of 8-8-coupled aryldihydronaphthalene product of 5-Br-feruloytyamide was higher than that of tert-butyl substituted precursor under FeCl3·6H2O-acetone-water oxidative condition.

关 键 词：oxidative coupling biomimetic synthesis regioselectivity liganamides canabisin D 

分 类 号：O643.36[理学—物理化学] TB333[理学—化学]