基于氢键的阴离子识别主体分子的研究进展  

Recent Development of Anion Receptors Based on Hydrogen Bonding

作　　者：李勇军[1] 刘辉彪[1] 李玉良[1] 

机构地区：[1]中国科学院化学研究所有机固体院重点实验室,北京100190

出　　处：《无机化学学报》2015年第9期1687-1704,共18页Chinese Journal of Inorganic Chemistry

基　　金：国家自然科学基金(No.21290190;21322301)资助项目

摘　　要：阴离子在生物学、医学、催化以及环境等方面逐渐得到广泛认识与重视,阴离子受体研究在跨膜离子输运、化学传感、模拟酶催化有机化学反应等方面亦有光明的应用前景。本文根据酰胺、脲与硫脲、吲哚吡咯、三氮唑、铵盐、胍盐、咪唑、羟基等不同的氢键单元,总结基于氢键的阴离子识别主体分子的研究进展。The important roles of anions in biology, medicine, catalysis and environmental science have been widely recognized. Anion receptors showed bright application prospects in the trans epithelial ion transportation, chemical sensing, simulation of enzyme catalyzed organic reactions. Here we summarize the recent progress of anion receptors based on different hydrogen bonding units such as amide, urea/thiourea, indole/pyrroles, triazole, ammonium, guanidinium, imidazole, hydroxyl groups.

关 键 词：阴离子识别 主体分子 氢键 

分 类 号：O641.3[理学—物理化学] O641.4[理学—化学]