碳骨架-气相色谱法测定电子电气材料中六溴环十二烷  

GC Determination of Hexabromocyclododecane in Electronic and Electrical Materials Based on Carbon Skeleton

作　　者：阮毅 叶典贤 方正 

机构地区：[1]浙江省检验检疫科学技术研究院,杭州311200

出　　处：《理化检验（化学分册）》2015年第8期1093-1095,共3页Physical Testing and Chemical Analysis(Part B:Chemical Analysis)

基　　金：国家质量监督检验检疫总局课题(2010IK197)

摘　　要：提出了碳骨架-气相色谱法测定电子电气材料中六溴环十二烷的方法。样品经二氯甲烷-丙酮（1＋2）混合液超声提取30min后用正己烷进行溶剂置换，在催化反应衬管中进行钯催化氢化反应。用HP-5MS毛细管色谱柱分离，氢火焰离子化检测器检测。六溴环十二烷的质量浓度在1．25～80．0mg·L1范围内与其峰面积呈线性关系，方法的测定下限（10S／N）为10mg·kg-1。加标回收率在78．8％～106％之间，测定值的相对标准偏差（n=8）为2．1％～5．6％之间。A method of GC for the determination of hexabromocyclododecane in electronic and electrical materials based on carbon skeleton was proposed. The sample was ultrasonically extracted with the mixture of dichloromethane-acetone （1 ＋ 2） for 30 min, and then the solvent was displaced with n-hexane. Catalytic hydrogenation reaction with palladium was conducted on the catalytic liners. The analyte was separated on HP-5MS capillary column and detected by FID. Linear relationship between values of peak area and mass concentration of hexabromocyclododecane was obtained in the range of 1.25--80. 0 mg· L-1, with detection limit （10S/N） of 10 mg· kg-1. Values of recovery found by standard addition method were in the range of 78. 8%- 106%, and values of RSD＇s （n=8） in the range of 2. 1%-5. 6%.

关 键 词：气相色谱法 电子电气材料 六溴环十二烷 碳骨架 

分 类 号：O657.7[理学—分析化学]