1,1'-二茂铁二甲酸的制备  

Synthesis of 1,1'-Ferrocenedicarboxylic Acid

作　　者：汪洋[1] 乔庆东[1] 李琪[1] 万玉荣[1] 高培玉[1] 

机构地区：[1]辽宁石油化工大学化学化工与环境学部,辽宁抚顺113001

出　　处：《当代化工》2015年第8期1774-1777,共4页Contemporary Chemical Industry

基　　金：辽宁省教育厅科技攻关项目;项目号:L2011057

摘　　要：二茂铁及其衍生物具有特殊的夹层状分子结构,因而具有诸多独特的物理和化学性质,在多个领域有着广阔的应用和研究价值。研究了对二茂铁进行乙酰化,制取1,1'-二乙酰基二茂铁的合成方法,并进而制备其氧化产物,制取1,1'-二茂铁二甲酸,并对合成条件进行优化。Ferrocene and its derivatives have sandwich-like special molecular structure, so they have many unique physical and chemical properties, and have been studied and applied widely in many fields. In this paper, preparation process of 1,1＇-ferrocenedicarboxylic acid was studied, including synthesis of 1,1＇-diacetylferrocene by acetylation of ferrocene, and preparation of its oxidation products. At last, the synthesis conditions were optimized.

关 键 词：二茂铁 1 1'-二茂铁二甲酸 1 1'-二乙酰基二茂铁 乙酰化 

分 类 号：TQ203[化学工程—有机化工]