含有轴向配体的酞菁金属材料的合成与应用进展  

Progresses in Synthesis and Application of Metal Phthalocyanines with Axial Ligands

作　　者：崔娜[1] 井晓慧[1] 程振华[1] 卜婷婷[1] 朱丽君[1] 夏道宏[1] 

机构地区：[1]中国石油大学(华东)重质油国家重点实验室,山东青岛266580

出　　处：《石油化工》2015年第8期1016-1023,共8页Petrochemical Technology

基　　金：中央高校基本科研业务费专项资金(14CX06114A)

摘　　要：近几年含有轴向配体的酞菁金属材料的合成与应用取得突飞猛进的发展,尤其在太阳能电池材料方面的研究与应用更为显著。介绍了含有轴向配体的酞菁金属配合物的结构特征,阐述了这类酞菁金属材料在合成方面的研究进展以及在催化氧化、光盘信息记录、太阳能电池、医学等领域的应用进展,并对其发展前景进行了展望。Metal phthalocyanines with axial ligands are a kind of coordination compounds with the axial ligands coordinated to central metallic atoms. The two-dimensional macrocyclic conjugated electronic systems can improve the solubility,stability and optoelectr onic properties of the phthalocyanines. In recent years,great achievements have been made in the synthesis and application of the metal phthalocyanines with the axial ligands,especially in the field of solar cell materials. The structure characteristics and synthesis of the metal phthalocyanines with the axial ligands,as well as their application in catalytic oxidation,optical information recording,nonlinear optics,solar cell and medicine,were reviewed. Their development prospects were discussed.

关 键 词：酞菁金属 轴向配体 合成 光电材料 

分 类 号：TQ613.5[化学工程—精细化工]