固溶温度对S32760双相不锈钢组织与耐点蚀性能的影响  

EFFECT OF SOLUTION TEMPERATURE ON MICROSTRUCTURE AND PITTING CORROSION RESISTANCE OF S32760 DUPLEX STAINLESS STEEL

作　　者：陈雨来[1] 罗照银 李静媛[2] 

机构地区：[1]北京科技大学冶金工程研究院,北京100083 [2]北京科技大学材料科学与工程学院,北京100083

出　　处：《金属学报》2015年第9期1085-1091,共7页Acta Metallurgica Sinica

基　　金：国家自然科学基金项目51174026;十二五国家科技支撑计划项目2012BAE04B02资助~~

摘　　要：利用OM,EPMA,SEM,EDS,TEM等研究了固溶温度对S32760双相不锈钢热轧板显微组织的影响及合金元素的分布特征,并通过电化学工作站测定了材料的耐点蚀性能.结果表明,S32760双相不锈钢在1080℃以上高温固溶过程中,N元素从g相扩散转移至d相中.若固溶后缓慢冷却,则N原子又重新迁移回g相中;如果固溶后水冷,则N原子来不及扩散,于d相中原位弥散析出Cr2N颗粒.Cr2N颗粒的数量由淬火前的固溶温度决定,温度越高数量越多.当固溶温度从1100℃升至1300℃时,d相中N的固溶度快速上升,其显微硬度由281 HV提高至345 HV;而g相由于相比例降低也使得N的浓度间接上升,显微硬度由290 HV升至314 HV.同时,由于实验钢中含有W,S32760双相不锈钢热轧板在1040℃以下热处理有s相析出,因此其固溶水冷温度区间较窄,最佳固溶温度为1060℃.此温度保温60 min后水冷,试样中无析出物,Brinell硬度为249 HBW,点蚀电位为1068 m V,维钝电流密度为1.48×10-4A/cm2.In order to obtain the optimal corrosion resistance, the characteristics of microstructure and alloy elements distribution of S32760 duplex stainless steel were studied after solid solution treatment at various temperatures from 1000 ℃ to 1300 ℃ by means ofOM, EPMA, SEM, EDS and TEM. In addition, the pitting corrosion resistance was measured by the electrochemical workstation. The results show that the N atoms diffused into δ phase from γ phase during solution treatment when the temperature was higher than 1080 ℃. N atoms migrated back into γ phase when the subsequent cooling was slow enough. However, Cr2N phase in situ precipitated during quenching because there was not enough time for the N atoms to diffuse back into γ phase. Cr2N particles increased with the solution temperature increasing. Furthermore, σ phase precipitated when the tested sheet was heat treated at or below 1040 ℃ due to the high content of N. Thus it is obvious that the solution temperature range of the S32750 duplex stainless steel is quite narrow, which is between 1040℃ and 1080 ℃, and it is confirmed that the optimal temperature is 1060℃. After treated at 1060 ℃ for 60 min, the Brinell hardness of S32760 steel is 249 HBW, pitting potential is up to 1068 mV and the passive current density is as low as 148×10^-4A/cm^2.

关 键 词：双相不锈钢 固溶处理 析出 耐点蚀性能 

分 类 号：TG142.71[一般工业技术—材料科学与工程]