柱芳烃合成及应用研究进展  

Progress in the synthesis and application of pillar[n]arene

作　　者：卜婷婷 崔娜 朱丽君[1] 周玉路[1] 项玉芝[1] 夏道宏[1] 

机构地区：[1]中国石油大学(华东)化学工程学院,重质油国家重点实验室,山东青岛266580

出　　处：《化工进展》2015年第9期3267-3278,共12页Chemical Industry and Engineering Progress

基　　金：国家自然科学基金面上项目(21376265)

摘　　要：柱芳烃是一类结构对称、由对苯二酚或对苯二酚醚通过亚甲基对位桥联的新型"柱"状大环低聚超分子主体化合物。本文主要回顾了烷氧基柱芳烃、水溶性柱芳烃、两亲性柱芳烃的合成发展过程,介绍了柱芳烃的结构与构象,柱芳烃及其衍生物的主客体化学,阐述了它们在构筑超分子自组装体系、医药、生物、相转移催化方面的应用研究进展。目前,柱[5,6]芳烃的合成方法已经比较成熟,而高阶柱芳烃的合成仍有待进一步改善,同时,随着研究的不断深入,柱芳烃及其衍生物将有望用于催化、生物模拟、石油化工等更广泛的领域。Pillararene is a kind of new ＂column＂ macrocyclic supramolecular polymer with symmetrical structure. It is formed by hydroquinone or hydroquinone ether para-bridged by methylene. In this paper,it is aimed to review progress in the synthesis of alkoxy,water-soluble and amphipathic pillararene,to introduce the structure and conformation of pillararene,the host-guest properties of pillararene and their derivatives,to elaborate the application progress of pillararenes in the field of supramolecular self-assembly,medicine,biology and phase transfer catalytic aspects. So far,the synthesis method of pillar[5,6]arene has been well established,while the high-level pillararene needs to improve. Meanwhile,with the deepening of research,pillararene and their derivatives are expected to be used in the areas of catalysis,biologic simulation,and petrochemistry.

关 键 词：柱芳烃 超分子 合成 分子识别 自组装 

分 类 号：O641.3[理学—物理化学]