吸波材料结构、性能及应用研究进展  

Study on the structure,properties and application of microwave absorbing materials

作　　者：胡小赛 沈勇[1] 王黎明[1] 俞菁[1] 邢亚均 

机构地区：[1]上海工程技术大学服装学院,上海201620

出　　处：《应用化工》2015年第9期1741-1746,共6页Applied Chemical Industry

基　　金：上海市教委科研创新(重点)项目(12zz180)

摘　　要：综述了碳系吸波材料、导电高聚物、手性吸波材料、席夫碱类吸波材料等吸波材料的最新研究应用现状,并展望了吸波材料未来发展趋势。碳纳米管/石墨烯等新型碳系吸波材料结合了炭材料和纳米材料的良好的导电性能和质量轻等优点,具有优异的吸波性能;导电高聚物吸波材料具有较强的可设计性和较低的密度,使得其成为一类具有较大发展潜力的新型吸波材料;手性吸波材料具有手性参数可调、吸波频带宽等优点,通过调整手性参数,可以实现有针对性的微波吸收;席夫碱类吸波材料可通过设计合成长链共轭结构的席夫碱及其金属络合物、引进手性螺旋结构等来提高席夫碱吸波材料的吸波性能。由于吸波材料的性能是影响雷达隐身的关键因素,而传统的吸波材料存在吸收频带窄、吸收强度弱及密度大等问题,新型吸波材料的研究应用成为当前功能材料领域的热点之一。Microwave absorbing materials including carbon-based materials, conductive polymers, chiral materials and Schiff base materials were reviewed in detail and the future developments of the microwave absorbing materials were prospected. Carbon-based materials such as carbon nanotubes/graphene exhibit excellent microwave absorption property,combining the advantages of carbon materials and nano-materials like good conductivity,light weight,etc. Conductive polymer absorbing materials have potential application in microwave absorbing field for their low density and designability;Chiral absorbing materials with excel-lent absorbing properties such as adjustable chiral parameter and wide absorbing band can obtain directed microwave absorbtion by adjusting chiral parameters;Absorbing properties of Schiff base materials can be significantly enhanced through micro-structure control such as with long-chain conjugated schiff base and its’ salt, or with chirality. Though microwave absorbing materials play an important role in the radar stealth,because of traditional microwave absorbing materials with many drawbacks such as narrow absorp-tion frequency band,low absorption capacity and high density,so that novel microwave absorbing materials have drawn considerable interests in the field of functional materials due to their unique electromagnetic properties.

关 键 词：碳系 导电高聚物 手性吸波材料 席夫碱 

分 类 号：TQ050.4[化学工程] TN972[电子电信—信号与信息处理]