三维四嗪基多孔共价有机骨架材料的合成及其吸附性能（英文）  

The synthesis and gas selective adsorption of a 3D porous tetrazine-based covalent organic framework

作　　者：占凯峰 孙林[2] 朱冬冬[1] 周德望 任世斌[1,2] 

机构地区：[1]台州学院医药化工学院,浙江台州317000 [2]南京大学化学化工学院,江苏南京210093

出　　处：《化学研究》2015年第4期384-388,共5页Chemical Research

基　　金：Zhejiang Provincial Natural Science Foundation of China(LY12B01006);State Key Laboratory of Analytical Chemistry for Life Sciences(SKLACLS1206);University Students’ Science And Technology Innovation Program of Zhejiang Province(2014R428014);University Students’ Science and Technology Innovation Program of Taizhou

摘　　要：通过半刚性单体四(4-氰基氧甲基)甲烷(T-4-CPMM)和水合肼在单质硫催化下发生聚合反应,成功合成了四嗪基三维多孔共价有机骨架材料Tzc-COF-1(1).这是首例使用半刚性单体制备多孔共价有机骨架材料.此外,还研究了该化合物的热稳定性及其气体的吸附性质.A new porous tetrazine-based covalent organic framework,Tzc-COF-1（1）,has been successfully prepared by the condensation reaction of semi-rigid monomer tetrakis[（4-cyanophenoxy）methyl]methane（T-4-CPMM）and hydrazine hydrate under the catalysis of sulphur.This is the first report,where semi-rigid monomers are used to construct a porous organic framework.In addition,its thermal stability and gas adsorption property are also discussed.

关 键 词：共价有机骨架材料 半刚性单体 选择性吸附 四嗪 

分 类 号：O627.8[理学—有机化学]