十六烷基二甲基乙基溴化铵与NH_4SCN缓蚀协同效应  

Synergistic Corrosion Inhibition Effect of Cetyldimethylethylammonium Bromide and NH_4SCN

作　　者：向云刚 崔益顺[1] 谯康全[2] 

机构地区：[1]四川理工学院材料与化学工程学院,四川自贡643000 [2]四川理工学院分析测试中心,四川自贡643000

出　　处：《表面技术》2015年第10期105-110,共6页Surface Technology

摘　　要：目的研究十六烷基二甲基乙基溴化铵(CDAB)与NH4SCN在硫酸介质中对Q235钢的缓蚀协同效应,并探讨其缓蚀机理和性能,以期为工业实际生产提供理论数据。方法运用失重法研究CDAB质量浓度与缓蚀率的关系,通过失重法、动电位极化曲线法和交流阻抗法分析CDAB与NH4SCN复配后的缓蚀率和缓蚀机理。结果仅添加CDAB时,缓蚀率随着CDAB质量浓度增大而增大,但缓蚀性能并不显著,当质量浓度为10 mg/L时缓蚀率仅为85.07%;当CDAB与30 mg/L的NH4SCN复配后,缓蚀率显著提高到96.73%,能有效抑制Q235钢在0.5 mol/L硫酸介质中的腐蚀。极化试验结果显示,该复配缓蚀剂是一种以控制阳极反应为主的混合型缓蚀剂,缓蚀率随CDAB质量浓度增大而增大,与交流阻抗法、失重法试验结果相一致。复配缓蚀剂在Q235钢表面的吸附服从Langmiur吸附等温模型,吸附吉布斯自由能ΔG0=-48.33 k J/mol,为自发吸附。结论 CDAB与NH4SCN在0.5 mol/L硫酸介质中具有优异缓蚀协同效应,能有效抑制腐蚀介质对Q235钢在的腐蚀,复配缓蚀剂具有较高的缓蚀率。Objective In order to provide theoretical data for industrial production,the synergistic corrosion inhibition effect of cetyldimethylethylammonium bromide（ CDAB） and NH4SCN for Q235 steel was investigated in 0. 5 mol / L sulfuric acid solution,and the corrosion inhibition mechanism and performance were explored. Methods Firstly,the relationship between the corrosion inhibition efficiency and the concentration of CDAB was studied by the weight loss method. Then,the corrosion inhibition efficiency and mechanism of the compound inhibitor were analyzed by weight loss measurements,potentiodynamic polarization curves and electrical impedance spectroscopy（ EIS）. Results The results of weight loss method showed that CDAB had a low corrosion inhibition efficiency when acted alone,and the inhibition efficiency increased with the increasing CDAB concentration. The corrosion inhibition efficiency was only 85. 07% when the concentration of CDAB was 10 mg / L,while the inhibition efficiency increased to96. 73% when CDAB was compounded with 30 mg / L NH4 SCN. The experimental results revealed that the corrosion of Q235 steel in 0. 5 mol / L H2SO4 solution was strongly suppressed by the compound inhibitor. The polarization curve results showed that the compound inhibitor used in this paper was a mix-type inhibitor which mainly retarded anodic process,and the inhibition efficiency increased with the increasing CDAB concentration. The anti-corrosion performances determined by the potentiodynamic polarization curve,weight loss method and EIS were almost consistent. The adsorption of the compound inhibitor on Q235 steel surface abided the Langmiur＇s adsorption isotherm and the Gibbs free energy of adsorption ΔG0was-48. 33 k J / mol. The adsorption was a spontaneous chemisorption process. Conclusion Composite of CDAB and NH4 SCN showed excellent synergistic effect in the presence of0. 5 mol / L sulfuric acid solution,and the corrosion of Q235 steel in 0. 5 mol / L sulfuric acid solution was effectively suppressed by the co

关 键 词：Q235钢 十六烷基二甲基乙基溴化铵 NH4SCN 协同效应 缓蚀性能 

分 类 号：TG174.42[金属学及工艺—金属表面处理]