A Green and Efficient Trinitration System for Aromatic Compounds with Bi（NO3）3·5H2O/[HMIMICIO4 as Catalyst in HNO3/Ac2O  

作　　者：SUN Weizhi YU Shitao XIAN Mo 

机构地区：[1]CAS Key Laboratory of Biobased Materials, Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao 266101, P. R. China [2]College of Chemical Engineering, Qingdao University of Science and Technology, Qingdao 266042, P. R. China

出　　处：《Chemical Research in Chinese Universities》2015年第5期761-765,共5页高等学校化学研究（英文版）

基　　金：Supported by the National Natural Science Foundation of China（No.21376255）.

摘　　要：To investigate the green trinitration method of aromatic compounds, with Lewis acid/ionic liquid as catalyst and HNOJAc2O as nitration reagent, a Lewis acid/ionic liquid/HNO3/Ac2O system was established. In various combinations of Lewis acids and ionic liquids, Bi（NO3）3-5H2O/[HMIM]CIO4 proved to be a very efficient catalyst for the trinitration of activated aromatic compounds and reusable for 3 times. Reaction conditions for the trinitration were optimized and yields of the trinitro products were from mild to excellent. This sulfuric acid-free system has the advantages of strong trinitration ability, low environment pollution, low toxicity, low cost and high potential for industrial application.To investigate the green trinitration method of aromatic compounds, with Lewis acid/ionic liquid as catalyst and HNOJAc2O as nitration reagent, a Lewis acid/ionic liquid/HNO3/Ac2O system was established. In various combinations of Lewis acids and ionic liquids, Bi（NO3）3-5H2O/[HMIM]CIO4 proved to be a very efficient catalyst for the trinitration of activated aromatic compounds and reusable for 3 times. Reaction conditions for the trinitration were optimized and yields of the trinitro products were from mild to excellent. This sulfuric acid-free system has the advantages of strong trinitration ability, low environment pollution, low toxicity, low cost and high potential for industrial application.

关 键 词：Green trinitration Aromatic compound Lewis acid Ionic liquid Acetyl nitrate 

分 类 号：TQ221.213[化学工程—有机化工] O625[理学—有机化学]