有机或金属-有机二维纳米材料的制备与应用（英文）  

Preparation and Applications of Two-Dimensional Crystals Based on Organic or Metal-Organic Materials

作　　者：李绍周[1] 黄晓[2] 张华[3] 

机构地区：[1]江苏省有机电子与信息显示重点实验室南京邮电大学先进材料研究院,南京210023 [2]柔性电子重点实验室先进生物与化学制造协同创新中心南京工业大学先进材料研究院,南京211816 [3]材料科学与工程学院新加坡南洋理工大学,新加坡639798

出　　处：《化学学报》2015年第9期913-923,共11页Acta Chimica Sinica

基　　金：supported by MOE under AcRF Tier 2(ARC 26/13,No.MOE2013-T2-1-034;ARC 19/15,No.MOE2014-T2-2-093);AcRF Tier 1(RGT18/13,RG5/13);NTU under Start-Up Grant(M4081296.070.500000);iFood Research Grant(M4081458.070.500000);Singapore Millennium Foundation in Singapore;the National Natural Science Foundation of China(GZ213054,51322202)in China;the Natural Science Foundation of Jiangsu Province(BK20130927);supported by the Singapore National Research Foundation under its Environmental&Water Technologies Strategic Research Programme and administered by the Environment&Water Industry Programme Office(EWI)of the PUB;conducted by NTU-HUJ-BGU Nanomaterials for Energy and Water Management Programme under the Campus for Research Excellence and Technological Enterprise(CREATE);supported by the National Research Foundation,Prime Minister’s Office,Singapore~~

摘　　要：对石墨烯等二维材料的研究进一步引发了人们对相似结构的其他有机、金属-有机二维层状纳米材料的浓厚兴趣.这些二维材料由于其优异的化学可剪裁性而受到关注,预期未来在电子器件、催化和小分子分离等方面具有广泛的用途.这篇综述系统地介绍了目前制备有机基二维材料的自上而下和自下而上的两大类方法,总结了有机基二维材料在生物识别、小分子分离和纯化以及电学方面的应用,最后讨论了有机基二维材料目前在制备和性质改进方面面临的问题和未来可能发展的研究方向.Besides graphene and transitional metal dichalcogenide nanosheets which have aroused tremendous research interest over the last decade, recently, two-dimensional（2D） organic or metal-organic nanosheets have also attracted increasing research interest. These ultrathin nanomaterials possess the long range structural order, the tunable surface properties, and/or controllable porosity, making them promising in a wide range of applications, such as electronics, optoelectronics, catalysis, molecular separation and so on. This review article aims to provide a brief overview on free-standing 2D nanosheets of organic or metal-organic materials that have been reported so far, especially focusing on their synthetic methods and possible applications.

关 键 词：二维材料 有机晶体 金属有机骨架材料 共价有机框架材料 

分 类 号：TB383.1[一般工业技术—材料科学与工程]