Progress in side-chain thiophene-containing polymers: synthesis, properties and applications  

作　　者：Yali Qiao Xiaodong Yin Chuanbing Tang 

机构地区：[1]Department of Chemistry and Biochemistry, University of South Carolina

出　　处：《Science China Chemistry》2015年第11期1641-1650,共10页中国科学（化学英文版）

基　　金：supported by the Office of Naval Research(N000141110191);South Carolina National Aeronautics and Space Administration Experimental Program to Stimulate Competitive Research(22-NE-USC_Tang)

摘　　要：In contrast to conventional main-chain conjugated polymers, incorporation of electronically active conjugated oligomers into non-conjugated polymer backbones as pendant groups represents a promising alternative strategy to developing novel electroactive polymer materials that are desirable for potential applications in organic electronics. This review focuses on polymers with thiophene in the side chain and summarizes the most important synthetic approaches to these polymers, including direct controlled polymerization techniques(e.g., ATRP, ROMP, and RAFT) as well as post-polymerization modifications. Additionally, various properties and applications of these polymers are discussed.In contrast to conventional main-chain conjugated polymers, incorporation of electronically active conjugated oligomers into non-conjugated polymer backbones as pendant groups represents a promising alternative strategy to developing novel electroactive polymer materials that are desirable for potential applications in organic electronics. This review focuses on polymers with thiophene in the side chain and summarizes the most important synthetic approaches to these polymers, including direct controlled polymerization techniques （e.g., ATRP, ROMP, and RAFT） as well as post-polymerization modifications. Additionally, various properties and applications of these polymers are discussed.

关 键 词：non-conjugated polymer THIOPHENE controlled polymerization post-polymerization modification organic electronics 

分 类 号：O631[理学—高分子化学]