铑催化线性氢甲酰化反应的研究进展  

Progresses in Rh-Catalyzed Linear Hydroformylation

作　　者：陈才友 吕辉[1] 张绪穆[1] 

机构地区：[1]武汉大学化学与分子科学学院,湖北武汉430072

出　　处：《石油化工》2015年第10期1149-1156,共8页Petrochemical Technology

基　　金：武汉大学基金项目(203273463);教育部"111"引智计划;国家自然科学基金项目(21372179)

摘　　要：介绍了氢甲酰化反应机理;综述了线性氢甲酰化配体的发展过程,包括双齿膦配体、三齿膦配体及四齿膦配体,双齿膦配体中重点介绍了Bisbi系列配体、Xantphos系列配体和具有大位阻的含亚磷酸酯键的Biphephos系列配体的结构及应用;并从配体的设计出发,简要地介绍了氢甲酰化的机理和影响线性氢甲酰化反应选择性的因素。对如何推动我国线性氢甲酰化工业的发展提出了展望。The mechanism of linear hydroformylation and the development history of ligands for the linear hydroformylation were reviewed briefly. Among bidentate ligands, tridentate ligands and tetradentate ligands, the Bisbi type ligands, Xantphos type ligands and Biphephos ligands with bulky substituting groups were discussed. Moreover, the mechanism and the factors influencing the regioselectivity of the linear hydroformylation were introduced. The prospects on how to promote the application of the liner hydrofomylation in industry were predicted.

关 键 词：线性氢甲酰化 铑催化剂 膦配体 

分 类 号：TQ032.41[化学工程]