紫外光引发聚合的研究与应用  

Researches and applications of UV-initiated polymerization

作　　者：马江雅[1,2] 付坤[1] 张源林 秦川[1] 赵相南 

机构地区：[1]安徽工业大学建筑工程学院,安徽马鞍山243002 [2]生物膜法水质净化与利用技术教育部工程研究中心,安徽马鞍山243002

出　　处：《化学研究与应用》2015年第10期1574-1580,共7页Chemical Research and Application

基　　金：国家自然科学基金项目(51408004)资助;安徽省大学生创新创业训练计划项目(AH201410360058)资助

摘　　要：紫外光引发聚合和接枝聚合作为一种绿色经济环保的聚合技术,已经在涂料、油墨、胶黏剂等领域取得了成功的研究和应用。与传统的热引发聚合相比,紫外光引发聚合具有操作简单、反应时间短、转化率高、常温下即可反应、成本低等优势,而得到广泛关注。论文对紫外光引发聚合的引发机理、聚合动力学和在一些新的领域的研究和应用进行评述,并对其发展趋势进行了展望。UV-initiated polymerization and graft polymerization,as a kind of environmentally friendly and economical poly-techniques,have been successfully studied and applied in various fields of coating,ink,adhesives. Compared with the traditional thermal-initiated polymerization,UV-initiated polymerization has the advantages of simple operation,shorter reaction time,reaction at room temperature,higher conversion rate,lower cost,etc. Thus this technique has received vigorous attention. In this paper,the initiation mechanism,kinetics and some researches and applications for UV-initiated polymerization in several new fields have been reviewed,and the prospect of UV-initiated polymerization has also been put forward.

关 键 词：紫外光引发聚合 引发机理 动力学 应用 

分 类 号：O644.1[理学—物理化学]