乙烯选择性齐聚催化剂的研究进展  

Advance in ethylene selective oligomerization catalyst

作　　者：毛国梁[1] 李颖[1] 张敏敏[1] 徐韬[1] 武可新[1] 

机构地区：[1]东北石油大学化学化工学院石油与天然气化工省重点实验室,黑龙江大庆163318

出　　处：《化工科技》2015年第5期63-69,共7页Science & Technology in Chemical Industry

基　　金：国家自然科学基金项目(20972025;U1362110);中国石油科技创新基金资助项目(2013D-5006-0503)

摘　　要：线性α-烯烃是一类有重要工业用途的化工原料,利用乙烯选择性齐聚法生产的α-烯烃具有线性化程度高,分离费用低,产品质量好等优点。近年来,在过渡金属催化乙烯选择性齐聚方面的研究取得了很多重要的进展。按配位金属分类,介绍了其配合物在选择性乙烯齐聚中的应用研究进展。Linearα-olefin is a class of important industrial chemical feedstock.α-Olefin produced by ethylene selective oligomerization method has the advantage of high linear degree,low separation costs,high quality etc.In recent years,a lot of important progress were achieved in the research field of transition metal catalyzed ethylene oligomerization.Development in ethylene oligomerization catalyzed by transition metal complexes was introduced according to the centrical metal in this review.

关 键 词：乙烯齐聚 催化剂 铬 镍 铁 钛 

分 类 号：TQ426.92[化学工程]