Vertical sections of Tb_(0.15)Ho_(0.85)Fe_y-Tb_(0.3)Dy_(0.7)Fe_y(y=1.85, 1.9, 2.0) in Tb-Dy-Ho-Fe system  

作　　者：王博文 黄文美 翁玲 孙英 曹淑瑛 王志华 

机构地区：[1]Province-Ministry Joint Key Laboratory of Electromagnetic Field and Electrical Apparatus Reliability, Hebei University of Technology

出　　处：《Journal of Rare Earths》2015年第11期1170-1174,共5页稀土学报（英文版）

基　　金：supported by the National Natural Science Foundation of China(51171057,51201055)

摘　　要：The x（Tb0.15Ho0.85Fey）＋（1–x）（Tb0.3Dy0.7Fey）（x=0, 0.1, 0.2, 0.3, 0.4, 0.5, 0.6, 0.7, 0.8, 0.9; y=1.85, 1.9, 2.0） samples were prepared by a vacuum arc furnace, and annealed at 1000 oC for 1 d and at 950 oC for a week. Three vertical sections of Tb0.15Ho0.85Fey-Tb0.3Dy0.7Fey（y=1.85, 1.9, 2.0） in the Tb-Dy-Ho-Fe system were determined using optical microscopy, scanning electron microscopy, energy dispersion X-ray spectroscopy, X-ray diffraction, and differential thermal analysis. These vertical sections consisted of two single-phase regions： L and（Tb,Dy,Ho）Fe2; four two-phase regions： L＋（Tb,Dy,Ho）Fe3, L＋（Tb,Dy,Ho）Fe2,（Tb,Dy,Ho）Fe2＋（Tb,Dy,Ho）Fe3, and（Tb,Dy,Ho）Fe2＋（Tb,Dy,Ho）. The high Ho content of（Tb,Dy,Ho）Fey alloys led to the elevation of the peritectic temperature of L＋（Tb,Dy,Ho）Fe3→（Tb,Dy,Ho）Fe2. The region of（Tb,Dy,Ho）Fe2 phase was shifted towards the side of rich-Ho with the Fe content increasing. It meant that the substitution of Ho for Dy or Tb had a marked effect on the solidification process of（Tb,Dy,Ho）Fe2 compounds.The x（Tb0.15Ho0.85Fey）＋（1–x）（Tb0.3Dy0.7Fey）（x=0, 0.1, 0.2, 0.3, 0.4, 0.5, 0.6, 0.7, 0.8, 0.9; y=1.85, 1.9, 2.0） samples were prepared by a vacuum arc furnace, and annealed at 1000 oC for 1 d and at 950 oC for a week. Three vertical sections of Tb0.15Ho0.85Fey-Tb0.3Dy0.7Fey（y=1.85, 1.9, 2.0） in the Tb-Dy-Ho-Fe system were determined using optical microscopy, scanning electron microscopy, energy dispersion X-ray spectroscopy, X-ray diffraction, and differential thermal analysis. These vertical sections consisted of two single-phase regions： L and（Tb,Dy,Ho）Fe2; four two-phase regions： L＋（Tb,Dy,Ho）Fe3, L＋（Tb,Dy,Ho）Fe2,（Tb,Dy,Ho）Fe2＋（Tb,Dy,Ho）Fe3, and（Tb,Dy,Ho）Fe2＋（Tb,Dy,Ho）. The high Ho content of（Tb,Dy,Ho）Fey alloys led to the elevation of the peritectic temperature of L＋（Tb,Dy,Ho）Fe3→（Tb,Dy,Ho）Fe2. The region of（Tb,Dy,Ho）Fe2 phase was shifted towards the side of rich-Ho with the Fe content increasing. It meant that the substitution of Ho for Dy or Tb had a marked effect on the solidification process of（Tb,Dy,Ho）Fe2 compounds.

关 键 词：Tb-Dy-Ho-Fe system phase relationship vertical section microstructure rare earths 

分 类 号：TB381[一般工业技术—材料科学与工程]