Recent Advances in Organic Reactions Catalyzed by Lanthanide(III) Complexes  

作　　者：陈瑞芳 钱长涛 

机构地区：[1]StateKeyLaboratoryofOrganometallicChemistry,ShanghaiInstituteofOrganicChemistry,ChineseAcademyofSciences,Shanghai200032,China [2]StateKeyLaboratoryofOrganometallicChemistry,ShanghaiInstituteofOrganicChem

出　　处：《Chinese Journal of Chemistry》2002年第5期407-419,共13页中国化学（英文版）

基　　金：ProjectsupportedbytheNationalNaturalScienceFoundationofChinaandtheMajorStateBasicResearchDevelopmentProgram(No.G2 0 0 0 0 4 80 0 7)

摘　　要：Lanthanide compounds have been attracting much attention in organic synthesis. Chiral Ln substituted BINOL have been widely studied in several asymmetric organic reactions. LnCl 3 and Ln(OTf) 3 have been expected to serve as Lewis acids and have been applied to many important synthetic reactions in a one pot manner. Ln(O i Pr) 3 exhibits some basic characters, which also can be utilized in some special organic transformation. This article deals with some lanthanides(III) complexes promoted organic reactions, which we have recently developed.Lanthanide compounds have been attracting much attention in organic synthesis. Chiral Ln substituted BINOL have been widely studied in several asymmetric organic reactions. LnCl 3 and Ln(OTf) 3 have been expected to serve as Lewis acids and have been applied to many important synthetic reactions in a one pot manner. Ln(O i Pr) 3 exhibits some basic characters, which also can be utilized in some special organic transformation. This article deals with some lanthanides(III) complexes promoted organic reactions, which we have recently developed.

关 键 词：LANTHANIDE chiral Ln  BINOL LnCl    3 Ln(OTf)    3 organic reaction 

分 类 号：O643.3[理学—物理化学]